Version: dev

GEOSChemGasPhase

GEOS-Chem fullchem gas-phase mechanism (~819 reactions, ~272 species). Migrated from GasChem.jl GEOSChemGasPhase via mtk2esm with sub-system rate-law inlining.

Domain
gaschem
Type
reaction_system
.esm schema
1.0.0
Source
components/gaschem/geoschem_fullchem.esm
Tags
#gaschem #reaction_system

Description

GEOS-Chem fullchem gas-phase mechanism (~819 reactions, ~272 species). Migrated from GasChem.jl GEOSChemGasPhase via mtk2esm with sub-system rate-law inlining.

Reference

_source_ref: GasChem.jl src/geoschem_fullchem.jl GEOS-Chem fullchem gas-phase mechanism (~819 reactions, ~272 species). Migrated from GasChem.jl GEOSChemGasPhase via mtk2esm with sub-system rate-law inlining.

Post-process workarounds applied (mdl-ode):

  • 64 max(expr, 0.0) rate clamps were rewritten to (a + abs(a))/2 by scripts/migrations/rewrite_max_in_esm.py because EarthSciASTCatalystExt._esm_to_symbolic does not accept the max op. File a follow-on bead in EarthSciAST to add max/min support and drop this stop-gap (same lifecycle as scripts/migrations/post_process_geoschem_fullchem.py).

Inline tests (mdl-ode): 3 pinned reference states (clean troposphere / polluted urban / upper troposphere) with expected species values from upstream GasChem.GEOSChemGasPhase via mtkcompile + Rosenbrock23. Generator: scripts/migrations/reference_values_geoschem_fullchem.jl. Cross-implementation tolerance rel=1e-3 (loose enough to absorb solver-tolerance and Catalyst path divergence between rxn_sys=false and the migrated flat ReactionSystem; tight enough to catch translation bugs). Reference timing on the workspace machine: GasChem build (rxn_sys=false, ODE-model path) = 1138 s, mtkcompile = 65.6 s, peak RSS during build ~8.2 GiB — inside the bead’s combined 60-min / 32-GiB budget. The migration kept num_density (mol/m³) but not P; tests override num_density = P / (R_GAS · T) per state to maintain (T, P) consistency with the bead-pinned states._

Parameters

NameUnitsDefaultDescription
j_330
j_1520
j_910
j_920
j_1290
k_cld20
j_1480
j_850
j_300
j_460
j_930
j_630
j_260
j_770
j_940
j_1550
j_1200
j_420
j_1470
j_700
j_1340
k_mt60
j_70
j_410
j_1150
j_270
j_1280
k_cld10
j_110
j_1140
j_790
j_1190
j_1050
j_1460
j_610
j_180
j_1090
j_1130
num_density_inv602214076000000000
j_1310
T298.15
j_810
j_100
j_230
j_470
j_1370
j_160
j_250
j_1000
j_1380
j_740
j_720
j_1060
j_280
j_290
j_1180
j_510
j_1040
j_1270
j_390
j_1350
j_1230
j_960
j_1220
j_890
j_220
j_440
j_1640
j_970
j_310
j_990
j_380
j_200
j_760
j_690
j_830
j_1570
j_860
j_750
j_1590
j_650
k_mt10
j_1390
j_1660
j_590
j_320
j_170
j_1490
j_1540
j_210
j_880
j_1530
j_1600
j_1080
j_10
j_1330
k_mt20
num_density44.834554813693856
j_640
j_430
j_800
k_mt50
j_1070
j_730
j_1110
j_1170
j_1320
j_1030
j_450
j_710
j_1210
k_mt30
j_1580
j_1410
j_240
j_340
j_620
j_490
j_1400
j_950
k_cld30
j_560
j_780
j_660
j_90
j_1100
j_60
j_1430
j_1650
j_900
j_1300
j_1010
j_150
j_130
k_cld40
j_680
j_870
j_1630
j_1610
j_1450
k_cld60
j_530
j_1500
j_1560
j_540
j_370
j_1120
j_30
k_mt40
j_80
j_140
j_820
j_120
j_980
j_500
j_1160
j_1240
j_1510
j_1260
j_1620
j_400
j_1360
j_1440
k_cld50
j_550
j_20
j_480
j_360
j_1250
j_190
j_1420
j_840

Species

SpeciesUnitsDefaultConstantDescription
RIPB0
MVKOHOO0
IHN40
CFC1130
LTRO2H0
IDHNDOO10
HCFC1230
CH2I20
N2O54e-06
IBr0
XRO20
CHCl30
SALCCL0
MONITA0
ETP0
NO0.0004
PYAC0
CH41800
C2H60
CHBr30
C2H20
ETNO30
HONIT0
IO0
RB3P0
HOI0
ISOP0
C4HVP10
HPETHNL0
ETOO0
O1D1e-06
RIPD0
MACR0
LISOPNO30
PRN10
H12110
PRPN0
BrO0
Br0
C2H40
MENO30
PAN0
IEPOXAOO0
H0
MCRENOL0
R4N10
HMHP0
IEPOXD0
NRO20
B3O20
HO24e-06
OH4e-06
CFC1150
HI0
RA3P0
MONITU0
IDC0
LBRO2N0
INA0
H2O24e-06
CH2O4e-06
CH2Br20
ClOO0
MTPA0
BALD0
MO24e-06
IHPOO20
MACR1OO0
CH2OO0
HCFC220
BENZO0
MVKN0
CH2ICl0
I20
CSL0
CH3CCl30
I2O30
ICl0
HBr0
Cl20
XYLE0
PPN0
HNO24e-06
BZCO30
SO40
N2O300
IHN20
LIMO0
HCFC141b0
MTPO0
PHEN0
RIPC0
OTHRO20
ITCN0
TOLU0
A3O20
HPALD40
ICHOO0
ETHP0
BZCO3H0
LXRO2H0
H2O18400000
AROMRO20
MGLY0
MAP0
LXRO2N0
KO20
LTRO2N0
Cl2O20
NPRNO30
IPRNO30
HNO34e-06
MCROHOO0
LNRO2N0
BRO20
ALK40
R4N20
INO2B0
C4HVP20
PIO20
O320
BENZP0
HPALD10
N4e-11
LIMO20
IDHNDOO20
O2210000000yes
CO100
ICHE0
IDHNBOO0
I2O20
MCRDH0
HCFC142b0
PIP0
BrCl0
HCOOH0
NIT0
GLYX0
HOCl0
ICPDH0
SALAAL1e-09Held at 1e-9 rather than 0 as a denominator guard (mdl-79g): reaction R1’s rate is k_mt1/SALAAL, so a 0 initial value makes the first RHS evaluation 0/0 and the whole RHS non-finite. SALAAL is also R1’s own substrate, so the division cancels the mass-action factor and the term reduces to k_mt1O3SO2 – the singularity is removable and any positive value collapses it. The value is inert here: SALAAL is produced by no reaction and consumed only through k_mt1..k_mt3, all of which default to 0. 1e-9 matches the seed the analyses in this file already use. Remove this default once the substrate-detection heuristic drop (mdl-79g) lands on EarthSciAST main and R1’s division is gone.
LNRO2H0
RCO30
HMS1e-06
ClNO30
PP0
NITs0
H13010
ACTA0
NAP0
IHPNBOO0
IHPNDOO0
ICNOO0
HMML0
IHPOO30
CO2355000
I2O40
IEPOXA0
MVKHP0
CH3CHOO0
ROH0
PRPE0
MPN0
IHOO10
ICN0
LBRO2H0
IHN10
EOH0
HPALD20
MCRHNB0
MACRNO20
OClO0
HPALD1OO0
LVOC0
HC5A0
RIPA0
IHPOO10
MACR1OOH0
ALD20
CH3Cl0
IDHDP0
MSA0
ATO20
H24020
HPALD30
ATOOH0
IDN0
OLND0
NPHEN0
C3H80
MCO30
MONITS0
DMS0
OIO0
HNO44e-06
ClO0
IONITA0
ITHN0
SO4s0
OCS9e-06
IONO20
ETHLN0
RCHO0
MCRHP0
O0
CFC1140
MVK0
INO2D0
BZPAN0
HPALD2OO0
Br20
IDHPE0
CCl40
IHN30
MVKHC0
IDNOO0
SALACL0
MOH0
Cl0
CH3I1e-11
MEK0
IEPOXBOO0
ETO0
MCT0
CH2IBr0
IEPOXB0
MCRHN0
MVKHCB0
MVKPC0
INPD0
ACET0
MPAN0
INDIOL0
HAC0
CFC120
ETHN0
BENZO20
CH3Br0
MVKDH0
TRO20
INPB0
OLNN0
SO21e-09Held at 1e-9 rather than 0 as a denominator guard (mdl-79g): reaction R12’s rate is k_cld6/SO2, so a 0 initial value makes the first RHS evaluation 0/0 and the whole RHS non-finite. SO2 is also R12’s own substrate, so the division cancels the mass-action factor and the singularity is removable – any positive value collapses the term. Unlike the SALAAL/SALCAL guards this value is NOT inert: SO2 has live chemistry under default parameters (R167 SO2+OH, and R344/R348 with the Criegee intermediates), so it is kept as small as the guard allows rather than at a physically suggestive level. 1e-9 matches the seed the analyses in this file already use. Remove this default once the substrate-detection heuristic drop (mdl-79g) lands on EarthSciAST main and R12’s division is gone.
PO20
BrNO20
ISOPNOO10.03
H2500yes
R4P0
N2781000000yes
RP0
MP4e-06
CH2Cl20
GLYC0
LISOPOH0
ISOPNOO20
AROMP50
BrNO30
CFC110
HCl0
NO20.0004
ETO20
R4O20
ClNO20
BENZ0
IONO0
RCOOH0
I0
IHOO40
PROPNN0
HOBr0
IDCHP0
NO34e-06
AROMP40
SALCAL1e-09Held at 1e-9 rather than 0 as a denominator guard (mdl-79g): reaction R4’s rate is k_mt4/SALCAL, so a 0 initial value makes the first RHS evaluation 0/0 and the whole RHS non-finite. SALCAL is also R4’s own substrate, so the division cancels the mass-action factor and the term reduces to k_mt4O3SO2 – the singularity is removable and any positive value collapses it. The value is inert here: SALCAL is produced by no reaction and consumed only through k_mt4..k_mt6, all of which default to 0. 1e-9 matches the seed the analyses in this file already use. Remove this default once the substrate-detection heuristic drop (mdl-79g) lands on EarthSciAST main and R4’s division is gone.
INO0

Expression Templates

arrhenius_M

Parameters: A, B

$$ A \cdot e^{\frac{B}{T}} \cdot num_{density} $$

arrhenius

Parameters: A, B

$$ A \cdot e^{\frac{B}{T}} $$

scaled_M

Parameters: A

$$ A \cdot num_{density} $$

troe_clamp_arr_M

Parameters: A, B, Fc, M0

$$ \frac{\frac{A \cdot e^{\frac{350.0}{T}} \cdot num_{density}}{B + \frac{Fc \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(M0 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}} \cdot num_{density}}{1.0 + M0 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left|\frac{A \cdot e^{\frac{350.0}{T}} \cdot num_{density}}{B + \frac{Fc \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(M0 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}} \cdot num_{density}}{1.0 + M0 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}}\right|}{2.0} $$

arrhenius_M_div_lin

Parameters: A, B, C

$$ \frac{A \cdot num_{density} \cdot e^{\frac{B}{T}}}{1.0 + C \cdot num_{density}} $$

jpl_pdep_long

Parameters: A, Fc, k0_300, n0, ninf

$$ \frac{A \cdot e^{0.0} \cdot Fc^{\frac{1.0}{1.0 + \log_{10}\left(k0_{300} \cdot \frac{300}{T}^{n0} \cdot num_{density}\right)^{2}}} \cdot \frac{300}{T}^{ninf} \cdot num_{density}^{2}}{1.0 + k0_{300} \cdot \frac{300}{T}^{n0} \cdot num_{density}} $$

arrhenius_clamp_M_lin_exp0

Parameters: A, B, C

$$ \frac{A \cdot \left(B + C \cdot T\right) \cdot e^{0} \cdot num_{density} + \left|A \cdot \left(B + C \cdot T\right) \cdot e^{0} \cdot num_{density}\right|}{2.0} $$

troe_clamp_jpl_alt

Parameters: A, Fc, B

$$ \frac{\frac{A \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2}}{\left(B + \frac{Fc \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left|\frac{A \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2}}{\left(B + \frac{Fc \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{Fc \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)}\right|}{2.0} $$

troe_M2_arr

Parameters: A, n_inf, k0_300, n_0

$$ \frac{A \cdot e^{0.0} \cdot \frac{300}{T}^{n_{inf}} \cdot num_{density}^{2} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(k0_{300} \cdot \frac{300}{T}^{n_{0}} \cdot num_{density}\right)^{2}}}}{1.0 + k0_{300} \cdot \frac{300}{T}^{n_{0}} \cdot num_{density}} $$

arrhenius_clamp_lin

Parameters: B, C

$$ \frac{0.000127669384112 \cdot \left(B + C \cdot T\right) \cdot e^{\frac{1300.0}{T}} \cdot num_{density} + \left|0.000127669384112 \cdot \left(B + C \cdot T\right) \cdot e^{\frac{1300.0}{T}} \cdot num_{density}\right|}{2.0} $$

Reactions

IDSubstratesProductsRate
R1SALAAL + O3 + SO2→SO4$$\frac{k_{mt1}}{SALAAL}$$
R2SALAAL + HCl→SALACL$$k_{mt2}$$
R3SALAAL + HNO3→NIT$$k_{mt3}$$
R4O3 + SO2 + SALCAL→SO4s$$\frac{k_{mt4}}{SALCAL}$$
R5HCl + SALCAL→SALCCL$$k_{mt5}$$
R6HNO3 + SALCAL→NITs$$k_{mt6}$$
R7SO2 + H2O2→SO4$$k_{cld1}$$
R8O3 + SO2→SO4$$k_{cld2}$$
R9SO2→SO4$$k_{cld3}$$
R10SO2 + CH2O→HMS$$k_{cld4}$$
R11HMS→SO2 + CH2O$$k_{cld5}$$
R12SO2 + HMS + OH→2 SO4 + CH2O$$\frac{k_{cld6}}{SO2}$$
R13NO + O3→NO2 + O2$$\mathrm{arrhenius_M}\left(A=0.0018066422280000002, B=-1500.0\right)$$
R14O3 + OH→HO2 + O2$$\mathrm{arrhenius_M}\left(A=0.0010237639292000002, B=-940.0\right)$$
R15O3 + HO2→OH + 2 O2$$\mathrm{arrhenius_M}\left(A=6.022140760000001 \times 10^{-6}, B=-490.0\right)$$
R16O3 + NO2→NO3 + O2$$\mathrm{arrhenius_M}\left(A=7.226568912 \times 10^{-5}, B=-2450.0\right)$$
R17O3 + MO2→HO2 + CH2O + O2$$\mathrm{arrhenius_M}\left(A=1.7464208204 \times 10^{-7}, B=-1000.0\right)$$
R182 OH→H2O + O$$\mathrm{scaled_M}\left(A=0.0010839853368\right)$$
R192 OH→H2O2$$\frac{0.07507099121983447 \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(\frac{1.24658313732 \times 10^{-16} \cdot num_{density}}{2.6 \times 10^{-17} \cdot T}\right)^{2}}} \cdot e^{0.0} \cdot num_{density}^{2}}{T \cdot \left(1.0 + \frac{1.24658313732 \times 10^{-16} \cdot num_{density}}{2.6 \times 10^{-17} \cdot T}\right)}$$
R20HO2 + OH→H2O + O2$$\mathrm{arrhenius_M}\left(A=0.028906275648000003, B=250.0\right)$$
R21H2O2 + OH→H2O + HO2$$\mathrm{scaled_M}\left(A=0.0010839853368\right)$$
R22NO + HO2→NO2 + OH$$\mathrm{arrhenius_M}\left(A=0.0019873064508, B=270.0\right)$$
R232 HO2→H2O2 + O2$$602214076.0 \cdot \left(1.2646495595999998 \times 10^{-15} \cdot e^{\frac{920.0}{T}} \cdot num_{density} + 3 \times 10^{-13} \cdot e^{\frac{460.0}{T}}\right) \cdot \left(1.0 + 8.430997064 \times 10^{-13} \cdot H2O \cdot num_{density} \cdot e^{\frac{2200.0}{T}}\right) \cdot num_{density}$$
R24CO + OH→HO2 + CO2$$\frac{0.0006419113741985848 \cdot e^{0} \cdot num_{density}^{2} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(\frac{1.06591891452 \times 10^{-18} \cdot \frac{300}{T}^{1.3} \cdot num_{density}}{1.1 \times 10^{-18} \cdot T}\right)^{2}}}}{T \cdot \left(1.0 + \frac{1.06591891452 \times 10^{-18} \cdot \frac{300}{T}^{1.3} \cdot num_{density}}{1.1 \times 10^{-18} \cdot T}\right)} + \frac{9.033211139999998 \times 10^{-5} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(4.301529114285714 \times 10^{-5} \cdot \frac{300}{T}^{6.1} \cdot num_{density}\right)^{2}}} \cdot e^{0} \cdot num_{density}}{1.0 + 4.301529114285714 \times 10^{-5} \cdot \frac{300}{T}^{6.1} \cdot num_{density}}$$
R25CH4 + OH→MO2 + H2O$$\mathrm{arrhenius_M}\left(A=0.0014754244862, B=-1775.0\right)$$
R26NO + MO2→NO2 + HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0016856935529761601, B=300.0\right)$$
R27NO + MO2→MENO3$$\mathrm{arrhenius_M}\left(A=5.0585982384 \times 10^{-7}, B=300.0\right)$$
R28MO2 + HO2→MP + O2$$\mathrm{arrhenius_M}\left(A=0.00024690777116, B=750.0\right)$$
R292 MO2→O2 + MOH + CH2O$$\frac{5.7210337219999994 \times 10^{-5} \cdot num_{density} \cdot e^{\frac{390.0}{T}}}{1.0 + 26.2 \cdot e^{\frac{-1130.0}{T}}}$$
R302 MO2→2 HO2 + 2 CH2O$$\frac{5.721033722 \times 10^{-5} \cdot num_{density} \cdot e^{\frac{390.0}{T}}}{1.0 + 0.04 \cdot e^{\frac{1130.0}{T}}}$$
R31MO2 + OH→1.74 HO2 + 0.13 MOH + 0.87 CH2O$$\mathrm{scaled_M}\left(A=0.09635425215999999\right)$$
R32MP + OH→MO2 + H2O$$\mathrm{arrhenius_M}\left(A=0.00160188944216, B=200.0\right)$$
R33MP + OH→H2O + OH + CH2O$$\mathrm{arrhenius_M}\left(A=0.0006865240466400001, B=200.0\right)$$
R34ATOOH + OH→H2O + ATO2$$\mathrm{arrhenius_M}\left(A=0.00160188944216, B=200.0\right)$$
R35ATOOH + OH→H2O + MGLY + OH$$\mathrm{arrhenius_M}\left(A=0.00068652404664, B=200.0\right)$$
R36OH + CH2O→CO + H2O + HO2$$\mathrm{arrhenius_M}\left(A=0.0033121774180000004, B=125.0\right)$$
R37NO2 + OH→HNO3$$\mathrm{jpl_pdep_long}\left(A=0.0006527912279985609, Fc=0.6, k0_{300}=0.03871376202857143, n0=3.0, ninf=3.0\right)$$
R38HNO3 + OH→NO3 + H2O$$\frac{2.3609282745947946 \times 10^{-7} \cdot num_{density}^{2} \cdot e^{\frac{1335.0}{T}}}{1.0 + \frac{3.9204136347599994 \times 10^{-22} \cdot num_{density} \cdot e^{\frac{1335.0}{T}}}{2.69 \times 10^{-23} \cdot e^{\frac{2199.0}{T}}}} + 1.4513359231599999 \times 10^{-5} \cdot e^{\frac{460.0}{T}} \cdot num_{density}$$
R39NO + OH→HNO2$$\frac{0.00025386325533277365 \cdot e^{0.0} \cdot \frac{300}{T}^{2.6} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.011709718144444445 \cdot \frac{300}{T}^{2.5} \cdot num_{density}\right)^{2}}} \cdot num_{density}^{2}}{1.0 + 0.011709718144444445 \cdot \frac{300}{T}^{2.5} \cdot num_{density}}$$
R40HNO2 + OH→H2O + NO2$$\mathrm{arrhenius_M}\left(A=0.010839853368, B=-390.0\right)$$
R41NO2 + HO2→HNO4$$\mathrm{jpl_pdep_long}\left(A=6.890574073318141 \times 10^{-5}, Fc=0.6, k0_{300}=0.028605168610000002, n0=3.1, ninf=3.4\right)$$
R42HNO4→NO2 + HO2$$\frac{54500373878000.0 \cdot e^{\frac{-10900.0}{T}} \cdot \frac{300}{T}^{3.4} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.02868440730421053 \cdot \frac{300}{T}^{3.1} \cdot num_{density}\right)^{2}}} \cdot num_{density}}{1.0 + 0.02868440730421053 \cdot \frac{300}{T}^{3.1} \cdot num_{density}}$$
R43HNO4 + OH→H2O + NO2 + O2$$\mathrm{arrhenius_M}\left(A=0.0007828782987999999, B=380.0\right)$$
R44NO3 + HO2→NO2 + OH + O2$$\mathrm{scaled_M}\left(A=0.002107749266\right)$$
R45NO + NO3→2 NO2$$\mathrm{arrhenius_M}\left(A=0.00903321114, B=170.0\right)$$
R46NO3 + OH→NO2 + HO2$$\mathrm{scaled_M}\left(A=0.013248709672000002\right)$$
R47NO3 + NO2→N2O5$$\mathrm{jpl_pdep_long}\left(A=0.0008703883039980811, Fc=0.6, k0_{300}=0.9033211139999999, n0=3.1, ninf=3.0\right)$$
R48N2O5→NO3 + NO2$$\frac{249316627464000.0 \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.9033211139999999 \cdot \frac{300}{T}^{3.1} \cdot num_{density}\right)^{2}}} \cdot e^{\frac{-10840.0}{T}} \cdot \frac{300}{T}^{3.0} \cdot num_{density}}{1.0 + 0.9033211139999999 \cdot \frac{300}{T}^{3.1} \cdot num_{density}}$$
R49HCOOH + OH→H2O + HO2 + CO2$$\mathrm{scaled_M}\left(A=0.0002408856304\right)$$
R50OH + MOH→HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0017464208204000002, B=-345.0\right)$$
R51NO3 + NO2→NO + NO2 + O2$$\mathrm{arrhenius_M}\left(A=2.709963342 \times 10^{-5}, B=-1260.0\right)$$
R52NO3 + CH2O→CO + HNO3 + HO2$$\mathrm{scaled_M}\left(A=3.4928416408 \times 10^{-7}\right)$$
R53ALD2 + OH→0.05 CO + 0.95 MCO3 + H2O + 0.05 HO2 + 0.05 CH2O$$\mathrm{arrhenius_M}\left(A=0.0027882511718800005, B=350.0\right)$$
R54ALD2 + NO3→MCO3 + HNO3$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=-1900.0\right)$$
R55MCO3 + NO2→PAN$$\mathrm{troe_M2_arr}\left(A=0.035178193953255776, n_{inf}=5.6, k0_{300}=6.28115756688172, n_{0}=4.1\right)$$
R56PAN→MCO3 + NO2$$\frac{0.035178193953255776 \cdot e^{0} \cdot \frac{300}{T}^{5.6} \cdot num_{density} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(6.28115756688172 \cdot \frac{300}{T}^{4.1} \cdot num_{density}\right)^{2}}}}{5.6005909068 \times 10^{-20} \cdot e^{\frac{14000.0}{T}} \cdot \left(1.0 + 6.28115756688172 \cdot \frac{300}{T}^{4.1} \cdot num_{density}\right)}$$
R57NO + MCO3→MO2 + NO2 + CO2$$\mathrm{arrhenius_M}\left(A=0.0048779340156, B=270.0\right)$$
R58C2H6 + OH→H2O + ETO2$$\mathrm{arrhenius_M}\left(A=0.00461295982216, B=-1020.0\right)$$
R59NO + ETO2→ALD2 + NO2 + HO2$$0.0015657565975999998 \cdot e^{\frac{365.0}{T}} \cdot \left(1.0 + \frac{\left(-0.000812987610463907\right) \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{\left(1.0 + \frac{0.000812987610463907 \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right) \cdot \left(1.0 + \frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)}\right) \cdot num_{density}$$
R60NO + ETO2→ETNO3$$\frac{1.272940714850921 \times 10^{-6} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot e^{\frac{365.0}{T}} \cdot num_{density}^{2}}{\left(1.0 + \frac{0.000812987610463907 \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right) \cdot \left(1.0 + \frac{0.000812987610463907 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)}$$
R61NO + OTHRO2→ALD2 + NO2 + HO2$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=365.0\right)$$
R62C3H8 + OH→B3O2$$\frac{0.0045768269776 \cdot num_{density} \cdot e^{\frac{-585.0}{T}}}{1.0 + 5.87 \cdot \frac{300}{T}^{0.64} \cdot e^{\frac{-816.0}{T}}}$$
R63C3H8 + OH→A3O2$$\frac{0.0045768269776 \cdot num_{density} \cdot e^{\frac{-585.0}{T}}}{1.0 + \frac{0.16999999999999998 \cdot e^{\frac{816.0}{T}}}{\frac{300}{T}^{0.64}}}$$
R64A3O2 + NO→RCHO + NO2 + HO2$$0.0017464208204000002 \cdot e^{\frac{350.0}{T}} \cdot \left(1.0 + \frac{\left(-0.002144616162546836\right) \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{\left(1.0 + \frac{0.002144616162546836 \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right) \cdot \left(1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)}\right) \cdot num_{density}$$
R65A3O2 + NO→NPRNO3$$\frac{3.745402318038145 \times 10^{-6} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2}}{\left(1.0 + \frac{0.002144616162546836 \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right) \cdot \left(1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)}$$
R66NO + PO2→ALD2 + NO2 + HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=350.0\right)$$
R67ALK4 + OH→R4O2$$\mathrm{arrhenius_M}\left(A=0.0054801480916, B=-405.0\right)$$
R68NO + R4O2→0.05 A3O2 + 0.32 ACET + 0.19 MEK + 0.19 MO2 + 0.32 ALD2 + 0.14 RCHO + NO2 + 0.18 B3O2 + 0.27 HO2 + 0.32 OTHRO2$$0.0016259780051999999 \cdot \left(1.0 + \frac{\left(-0.00918857248849498\right) \cdot num_{density} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}}}{\left(1.0 + \frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right) \cdot \left(1.0 + \frac{0.00918857248849498 \cdot num_{density} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}}}{1.0 + \frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right)}\right) \cdot e^{\frac{350.0}{T}} \cdot num_{density}$$
R69NO + R4O2→R4N2$$\frac{1.4940416765478667 \times 10^{-5} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}}}{\left(1.0 + \frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right) \cdot \left(1.0 + \frac{0.00918857248849498 \cdot num_{density} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}}}{1.0 + \frac{0.00918857248849498 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right)}$$
R70NO + R4N1→0.57 RCHO + 0.86 ALD2 + 2 NO2 + 0.57 CH2O$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=350.0\right)$$
R71NO + ATO2→MCO3 + NO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0016861994128000001, B=300.0\right)$$
R72KO2 + NO→0.93 MCO3 + 0.93 ALD2 + 0.93 NO2 + 0.07 R4N2$$\mathrm{arrhenius_M}\left(A=0.0016259780052, B=350.0\right)$$
R73NO + B3O2→ACET + NO2 + HO2$$\frac{3.487098709897583 \times 10^{-6} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}^{2} \cdot e^{\frac{360.0}{T}}}{\left(1.0 + \frac{0.002144616162546836 \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right) \cdot \left(1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)}$$
R74NO + B3O2→IPRNO3$$\frac{3.487098709897583 \times 10^{-6} \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}^{2} \cdot e^{\frac{360.0}{T}}}{\left(1.0 + \frac{0.002144616162546836 \cdot 0.411^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}}\right) \cdot \left(1.0 + \frac{0.002144616162546836 \cdot num_{density}}{0.826 \cdot e^{0.0} \cdot \frac{300}{T}^{8.1}}\right)}$$
R75NO + PRN1→ALD2 + 2 NO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=350.0\right)$$
R76NO3 + ALK4→HNO3 + R4O2$$\mathrm{arrhenius_M}\left(A=0.0016861994128000003, B=-3280.0\right)$$
R77R4N2 + OH→R4N1 + H2O$$\mathrm{scaled_M}\left(A=0.0009635425216\right)$$
R78ACTA + OH→MO2 + H2O + CO2$$\mathrm{arrhenius_M}\left(A=1.8969743393999998 \times 10^{-5}, B=920.0\right)$$
R79RCHO + OH→H2O + RCO3$$\mathrm{arrhenius_M}\left(A=0.0036132844560000004, B=410.0\right)$$
R80RCO3 + NO2→PPN$$\mathrm{jpl_pdep_long}\left(A=0.3263956139992804, Fc=0.6, k0_{300}=70.38865823376624, n0=8.700000000000001, ninf=8.9\right)$$
R81PPN→RCO3 + NO2$$\frac{0.32639561399928035 \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(70.38865823376624 \cdot \frac{300}{T}^{8.700000000000001} \cdot num_{density}\right)^{2}}} \cdot e^{0} \cdot \frac{300}{T}^{8.9} \cdot num_{density}}{5.4199266840000004 \times 10^{-20} \cdot e^{\frac{14000.0}{T}} \cdot \left(1.0 + 70.38865823376624 \cdot \frac{300}{T}^{8.700000000000001} \cdot num_{density}\right)}$$
R82NO + RCO3→0.07 A3O2 + NO2 + 0.27 B3O2 + 0.5 OTHRO2$$\mathrm{arrhenius_M}\left(A=0.0040348343092, B=340.0\right)$$
R83RCHO + NO3→HNO3 + RCO3$$\mathrm{scaled_M}\left(A=3.914391494 \times 10^{-6}\right)$$
R84ACET + OH→H2O + ATO2$$602214076.0 \cdot \left(1.33 \times 10^{-13} + 3.82 \times 10^{-11} \cdot e^{\frac{-2000.0}{T}}\right) \cdot num_{density}$$
R85A3O2 + MO2→0.75 RCHO + 0.25 ROH + HO2 + 0.75 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=0.00035651073299200004\right)$$
R86MO2 + PO2→0.25 MOH + 0.5 ALD2 + 0.09 RCHO + 0.25 ROH + HO2 + 1.25 CH2O + 0.16 HAC$$\mathrm{scaled_M}\left(A=0.00035651073299200004\right)$$
R87R4O2 + HO2→R4P$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=700.0\right)$$
R88R4N1 + HO2→R4N2$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=700.0\right)$$
R89ATO2 + HO2→0.15 MCO3 + 0.85 ATOOH + 0.15 OH + 0.15 CH2O$$\mathrm{arrhenius_M}\left(A=0.0005179041053599999, B=700.0\right)$$
R90KO2 + HO2→0.15 MCO3 + 0.15 ALD2 + 0.85 ATOOH + 0.15 OH$$\mathrm{arrhenius_M}\left(A=0.00010947316677326401, B=1300.0\right)$$
R91B3O2 + HO2→RB3P$$\mathrm{arrhenius_M}\left(A=9.121369947416518 \times 10^{-5}, B=1300.0\right)$$
R92HO2 + PRN1→PRPN$$\mathrm{arrhenius_M}\left(A=9.121369947416518 \times 10^{-5}, B=1300.0\right)$$
R93MEK + OH→KO2 + H2O$$\mathrm{arrhenius_M}\left(A=0.0007828782987999999, B=-25.0\right)$$
R94MO2 + ETO2→0.25 EOH + 0.75 ALD2 + HO2 + 0.75 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=0.0001806642228\right)$$
R95MO2 + OTHRO2→0.25 EOH + 0.75 ALD2 + HO2 + 0.75 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=0.0001806642228\right)$$
R96MEK + NO3→KO2 + HNO3$$\mathrm{scaled_M}\left(A=4.817712608 \times 10^{-7}\right)$$
R97MO2 + R4O2→0.09 MO2 + 0.07 RCHO + 0.16 ALD2 + 0.25 MOH + 0.35 MEK + 0.09 B3O2 + 0.64 HO2 + 0.16 OTHRO2 + 0.03 A3O2 + 0.16 ACET + 0.25 ROH + 0.75 CH2O$$\mathrm{scaled_M}\left(A=5.04053181612 \times 10^{-5}\right)$$
R98MO2 + R4N1→0.38 ALD2 + 0.54 RCHO + 0.25 ROH + 0.15 R4O2 + NO2 + 0.5 HO2 + 0.95 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=5.04053181612 \times 10^{-5}\right)$$
R99MO2 + ATO2→0.5 MOH + 0.3 MCO3 + 0.5 MGLY + 0.3 HO2 + 0.5 CH2O + 0.2 HAC$$\mathrm{arrhenius_M}\left(A=0.00045166055700000005, B=500.0\right)$$
R100KO2 + MO2→0.5 MCO3 + 0.5 ALD2 + 0.25 MEK + 0.25 ROH + 0.5 HO2 + 0.75 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=5.04053181612 \times 10^{-5}\right)$$
R101MO2 + B3O2→0.75 ACET + 0.25 ROH + HO2 + 0.75 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=5.04053181612 \times 10^{-5}\right)$$
R102MO2 + PRN1→0.5 ALD2 + 0.25 RCHO + 0.25 ROH + NO2 + 0.5 HO2 + 1.25 CH2O + 0.25 MOH$$\mathrm{scaled_M}\left(A=5.04053181612 \times 10^{-5}\right)$$
R103EOH + OH→ALD2 + HO2$$\mathrm{scaled_M}\left(A=0.0020174171546\right)$$
R104ROH + OH→RCHO + HO2$$\mathrm{arrhenius_M}\left(A=0.0027701847496, B=70.0\right)$$
R1052 ETO2→2 ALD2 + 2 HO2$$\mathrm{scaled_M}\left(A=2.4690777116 \times 10^{-5}\right)$$
R1062 OTHRO2→2 ALD2 + 2 HO2$$\mathrm{scaled_M}\left(A=2.4690777116 \times 10^{-5}\right)$$
R1072 ETO2→EOH + ALD2$$\mathrm{scaled_M}\left(A=1.6259780051999998 \times 10^{-5}\right)$$
R1082 OTHRO2→EOH + ALD2$$\mathrm{scaled_M}\left(A=1.6259780051999998 \times 10^{-5}\right)$$
R109ETO2 + HO2→ETP$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=700.0\right)$$
R110HO2 + OTHRO2→ETP$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=700.0\right)$$
R111A3O2 + HO2→RA3P$$\mathrm{arrhenius_M}\left(A=9.121369947416518 \times 10^{-5}, B=1300.0\right)$$
R112PO2 + HO2→PP$$\mathrm{arrhenius_M}\left(A=9.121369947416518 \times 10^{-5}, B=1300.0\right)$$
R113RCO3 + HO2→0.41 RP + 0.15 RCOOH + 0.03 A3O2 + 0.15 O3 + 0.12 B3O2 + 0.44 OH + 0.22 OTHRO2$$\mathrm{arrhenius_M}\left(A=0.00025895205268, B=1040.0\right)$$
R114PRPE + OH→PO2$$\mathrm{jpl_pdep_long}\left(A=1.6682442493296552, Fc=0.5, k0_{300}=106.54556729230768, n0=2.7, ninf=4.0\right)$$
R115O3 + PRPE→0.56 CO + 0.1 CH4 + 0.5 ALD2 + 0.12 CH3CHOO + 0.12 CH2OO + 0.28 MO2 + 0.28 HO2 + 0.36 OH + 0.5 CH2O$$\mathrm{arrhenius_M}\left(A=3.3121774180000003 \times 10^{-6}, B=-1880.0\right)$$
R116GLYC + OH→0.134 GLYX + 0.505 CO + 0.773 HO2 + 0.361 CO2 + 0.227 OH + 0.732 CH2O + 0.134 HCOOH$$0.004817712608 \cdot \frac{1.0 + \left(-11.0729\right) \cdot e^{\left(-0.0136986301369863\right) \cdot T} + \left
R117GLYC + OH→CO + HCOOH + OH$$0.004817712608 \cdot num_{density} \cdot \left(1.0 + \left(-1\right) \cdot \frac{1.0 + \left(-11.0729\right) \cdot e^{\left(-0.0136986301369863\right) \cdot T} + \left
R118PRPE + NO3→PRN1$$\mathrm{arrhenius_M}\left(A=0.000276416260884, B=-1156.0\right)$$
R119GLYX + OH→2 CO + HO2$$\mathrm{arrhenius_M}\left(A=0.0018668636356000002, B=340.0\right)$$
R120MGLY + OH→CO + MCO3$$\mathrm{scaled_M}\left(A=0.00903321114\right)$$
R121GLYX + NO3→2 CO + HNO3 + HO2$$\frac{0.0008430997064000001 \cdot \left(3.5 \times 10^{18} + 1.26163848922 \times 10^{17} \cdot num_{density}\right) \cdot num_{density} \cdot e^{\frac{-1860.0}{T}}}{3.5 \times 10^{18} + 2.52327697844 \times 10^{17} \cdot num_{density}}$$
R122NO3 + MGLY→CO + MCO3 + HNO3$$\mathrm{arrhenius_M}\left(A=0.00202343929536, B=-1860.0\right)$$
R123OH + HAC→MGLY + HO2$$0.0012947602634 \cdot e^{\frac{305.0}{T}} \cdot num_{density} \cdot \frac{1.0 + \left(-23.7\right) \cdot e^{\left(-0.016666666666666666\right) \cdot T} + \left
R124OH + HAC→0.5 CO + 0.5 MO2 + 0.5 HCOOH + OH + 0.5 ACTA + 0.5 CO2$$0.0012947602634 \cdot e^{\frac{305.0}{T}} \cdot \left(1.0 + \left(-1\right) \cdot \frac{1.0 + \left(-23.7\right) \cdot e^{\left(-0.016666666666666666\right) \cdot T} + \left
R125A3O2 + MCO3→MO2 + RCHO + HO2$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R126MCO3 + PO2→MO2 + ALD2 + HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R127A3O2 + MCO3→RCHO + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200001, B=500.0\right)$$
R128MCO3 + PO2→0.35 RCHO + ACTA + 0.65 HAC$$\mathrm{arrhenius_M}\left(A=0.00011261403221200001, B=500.0\right)$$
R129MO2 + RCO3→0.07 A3O2 + 0.27 B3O2 + HO2 + 0.5 OTHRO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R130MO2 + RCO3→RCOOH + CH2O$$\mathrm{arrhenius_M}\left(A=0.00011261403221200001, B=500.0\right)$$
R131PRPN + OH→0.791 PROPNN + 0.791 OH + 0.209 PRN1$$\mathrm{arrhenius_M}\left(A=0.0052874395872799995, B=200.0\right)$$
R132ETP + OH→0.64 ALD2 + 0.64 OH + 0.36 OTHRO2$$\mathrm{arrhenius_M}\left(A=0.00311946891368, B=200.0\right)$$
R133RA3P + OH→0.36 A3O2 + 0.64 RCHO + 0.64 OH$$\mathrm{arrhenius_M}\left(A=0.0031194689136800004, B=200.0\right)$$
R134RB3P + OH→0.791 ACET + 0.209 B3O2 + 0.791 OH$$\mathrm{arrhenius_M}\left(A=0.0052874395872799995, B=200.0\right)$$
R135R4P + OH→0.791 RCHO + 0.209 R4O2 + 0.791 OH$$\mathrm{arrhenius_M}\left(A=0.00528743958728, B=200.0\right)$$
R136RP + OH→RCO3$$\mathrm{arrhenius_M}\left(A=0.00036915722858800004, B=200.0\right)$$
R137PP + OH→0.209 PO2 + 0.791 OH + 0.791 HAC$$\mathrm{arrhenius_M}\left(A=0.00528743958728, B=200.0\right)$$
R138LVOC + OH→OH$$\mathrm{arrhenius_M}\left(A=0.0290267184632, B=-400.0\right)$$
R139MAP + OH→MCO3$$\mathrm{arrhenius_M}\left(A=0.00036915722858800004, B=200.0\right)$$
R140C2H6 + NO3→HNO3 + ETO2$$\mathrm{scaled_M}\left(A=8.430997064 \times 10^{-10}\right)$$
R1412 MCO3→2 MO2$$\mathrm{arrhenius_M}\left(A=0.00150553519, B=500.0\right)$$
R142MCO3 + MO2→MO2 + HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0010839853368, B=500.0\right)$$
R143MCO3 + MO2→ACTA + CH2O$$\mathrm{arrhenius_M}\left(A=0.0001204428152, B=500.0\right)$$
R144MCO3 + R4O2→0.05 A3O2 + MO2 + 0.32 ACET + 0.19 MEK + 0.32 ALD2 + 0.13 RCHO + 0.18 B3O2 + 0.27 HO2 + 0.32 OTHRO2$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R145MCO3 + ATO2→MO2 + MCO3 + CH2O$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R146KO2 + MCO3→MO2 + ALD2 + MCO3$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R147MCO3 + B3O2→MO2 + ACET + HO2$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R148MCO3 + R4N1→MO2 + 0.75 ALD2 + 0.57 RCHO + 0.3 R4O2 + NO2 + 0.39 CH2O$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R149MCO3 + PRN1→MO2 + ALD2 + NO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R150MCO3 + R4O2→MEK + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200001, B=500.0\right)$$
R151MCO3 + ATO2→MGLY + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200002, B=500.0\right)$$
R152KO2 + MCO3→MEK + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200002, B=500.0\right)$$
R153MCO3 + R4N1→RCHO + NO2 + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200002, B=500.0\right)$$
R154MCO3 + PRN1→RCHO + NO2 + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200001, B=500.0\right)$$
R155MCO3 + B3O2→ACET + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200002, B=500.0\right)$$
R156MCO3 + ETO2→MO2 + ALD2 + HO2$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R157MCO3 + OTHRO2→MO2 + ALD2 + HO2$$\mathrm{arrhenius_M}\left(A=0.00101171964768, B=500.0\right)$$
R158MCO3 + ETO2→ALD2 + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200002, B=500.0\right)$$
R159MCO3 + OTHRO2→ALD2 + ACTA$$\mathrm{arrhenius_M}\left(A=0.00011261403221200001, B=500.0\right)$$
R160MCO3 + RCO3→0.07 A3O2 + MO2 + 0.27 B3O2 + 0.5 OTHRO2$$\mathrm{arrhenius_M}\left(A=0.00150553519, B=500.0\right)$$
R1612 NO3→2 NO2 + O2$$\mathrm{arrhenius_M}\left(A=0.0005118819646, B=-2450.0\right)$$
R162MO2 + NO2→MPN$$\mathrm{jpl_pdep_long}\left(A=0.00036266179333253385, Fc=0.6, k0_{300}=0.08364084388888889, n0=2.6999999999999997, ninf=4.8\right)$$
R163MPN→MO2 + NO2$$\frac{6323247798000000.0 \cdot \frac{300}{T}^{4.8} \cdot num_{density} \cdot e^{\frac{-11234.0}{T}} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.083420155646438 \cdot \frac{300}{T}^{2.6999999999999997} \cdot num_{density}\right)^{2}}}}{1.0 + 0.083420155646438 \cdot \frac{300}{T}^{2.6999999999999997} \cdot num_{density}}$$
R164DMS + OH→MO2 + SO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.007226568912000001, B=-280.0\right)$$
R165DMS + OH→MO2 + 0.75 SO2 + 0.25 MSA$$\frac{6.230166947659597 \times 10^{-13} \cdot e^{\frac{5376.0}{T}} \cdot num_{density}^{2}}{1.0 + 2.1997499999999996 \times 10^{-6} \cdot e^{\frac{3644.0}{T}}}$$
R166DMS + NO3→MO2 + HNO3 + SO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.00011442067444000002, B=530.0\right)$$
R167SO2 + OH→SO4 + HO2$$\mathrm{troe_M2_arr}\left(A=0.00011967839179973613, n_{inf}=4.3, k0_{300}=0.124206653175, n_{0}=4.3\right)$$
R168O3 + Br→BrO + O2$$\mathrm{arrhenius_M}\left(A=0.009635425216, B=-780.0\right)$$
R169BrO + HO2→HOBr + O2$$\mathrm{arrhenius_M}\left(A=0.002709963342, B=460.0\right)$$
R170Br + HO2→HBr + O2$$\mathrm{arrhenius_M}\left(A=0.0028906275648, B=-310.0\right)$$
R171HBr + OH→Br + H2O$$\mathrm{arrhenius_M}\left(A=0.0033121774180000004, B=200.0\right)$$
R1722 BrO→2 Br + O2$$\mathrm{arrhenius_M}\left(A=0.0014453137824, B=40.0\right)$$
R1732 BrO→Br2 + O2$$\mathrm{arrhenius_M}\left(A=1.6861994128000003 \times 10^{-5}, B=860.0\right)$$
R174BrO + NO→Br + NO2$$\mathrm{arrhenius_M}\left(A=0.0052994838688000005, B=260.0\right)$$
R175BrNO3 + Br→Br2 + NO3$$\mathrm{scaled_M}\left(A=0.029508489724\right)$$
R176Br2 + OH→HOBr + Br$$\mathrm{arrhenius_M}\left(A=0.012646495595999998, B=240.0\right)$$
R177HOBr + O→BrO + OH$$\mathrm{arrhenius_M}\left(A=0.07226568912, B=-430.0\right)$$
R178HBr + O→Br + OH$$\mathrm{arrhenius_M}\left(A=0.0034928416408000003, B=-1500.0\right)$$
R179BrO + OH→Br + HO2$$\mathrm{arrhenius_M}\left(A=0.010237639292, B=250.0\right)$$
R180Br + NO3→BrO + NO2$$\mathrm{scaled_M}\left(A=0.009635425216\right)$$
R181Br + CH2O→CO + HO2 + HBr$$\mathrm{arrhenius_M}\left(A=0.010237639292, B=-800.0\right)$$
R182Br + ALD2→MCO3 + HBr$$\mathrm{arrhenius_M}\left(A=0.010839853368, B=-460.0\right)$$
R183ACET + Br→ATO2 + HBr$$\mathrm{arrhenius_M}\left(A=0.099967536616, B=-7000.0\right)$$
R184Br + C2H6→ETO2 + HBr$$\mathrm{arrhenius_M}\left(A=0.142122521936, B=-6411.0\right)$$
R185C3H8 + Br→A3O2 + HBr$$\mathrm{arrhenius_M}\left(A=0.05281417446520001, B=-4330.0\right)$$
R186Br + NO2→BrNO2$$\frac{0.00015231795319966418 \cdot e^{0.0} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.009367774515555555 \cdot \frac{300}{T}^{2.4} \cdot num_{density}\right)^{2}}} \cdot num_{density}^{2} \cdot \frac{300}{T}^{2.4}}{1.0 + 0.009367774515555555 \cdot \frac{300}{T}^{2.4} \cdot num_{density}}$$
R187BrO + NO2→BrNO3$$\mathrm{jpl_pdep_long}\left(A=0.0001958373683995682, Fc=0.6, k0_{300}=0.050030092467692314, n0=0.20000000000000018, ninf=3.1\right)$$
R188CHBr3 + OH→3 Br$$\mathrm{arrhenius_M}\left(A=0.0005419926684, B=-360.0\right)$$
R189OH + CH2Br2→2 Br$$\mathrm{arrhenius_M}\left(A=0.001204428152, B=-840.0\right)$$
R190CH3Br + OH→Br + H2O + HO2$$\mathrm{arrhenius_M}\left(A=0.0008551439879200001, B=-1150.0\right)$$
R191H2O + O1D→2 OH$$\mathrm{arrhenius_M}\left(A=0.098160894388, B=60.0\right)$$
R192O1D + N2→N2 + O$$\mathrm{arrhenius_M}\left(A=0.012947602634, B=110.0\right)$$
R193O1D + O2→O2 + O$$\mathrm{arrhenius_M}\left(A=0.019873064508000002, B=55.0\right)$$
R194O1D + H2→OH + H$$\mathrm{scaled_M}\left(A=0.07226568912\right)$$
R195N2O + O1D→O2 + N2$$\mathrm{arrhenius_M}\left(A=0.0278825117188, B=20.0\right)$$
R196N2O + O1D→2 NO$$\mathrm{arrhenius_M}\left(A=0.04366052051, B=20.0\right)$$
R197CH4 + O1D→MO2 + OH$$\mathrm{scaled_M}\left(A=0.07889004395600001\right)$$
R198CH4 + O1D→CH2O + H2$$\mathrm{scaled_M}\left(A=0.005419926684000001\right)$$
R199CH4 + O1D→HO2 + CH2O + H$$\mathrm{scaled_M}\left(A=0.021077492660000002\right)$$
R200O2 + O→O3$$3.613284456 \times 10^{-25} \cdot num_{density\,inv} \cdot e^{0} \cdot \frac{300}{T}^{2.4} \cdot num_{density}^{2}$$
R201O3 + O→2 O2$$\mathrm{arrhenius_M}\left(A=0.004817712608, B=-2060.0\right)$$
R202OH + H2→H2O + H$$\mathrm{arrhenius_M}\left(A=0.0016861994128000001, B=-1800.0\right)$$
R203OH + O→H + O2$$\mathrm{arrhenius_M}\left(A=0.010839853368, B=180.0\right)$$
R204HO2 + O→OH + O2$$\mathrm{arrhenius_M}\left(A=0.01806642228, B=200.0\right)$$
R205O3 + O1D→2 O2$$\mathrm{scaled_M}\left(A=0.07226568912\right)$$
R206O3 + O1D→O2 + 2 O$$\mathrm{scaled_M}\left(A=0.07226568912\right)$$
R207O + OCS→CO + SO2$$\mathrm{arrhenius_M}\left(A=0.012646495596, B=-2200.0\right)$$
R208OH + OCS→SO2 + CO2$$\mathrm{arrhenius_M}\left(A=6.624354836 \times 10^{-5}, B=-1200.0\right)$$
R209NO2 + O→NO + O2$$\mathrm{arrhenius_M}\left(A=0.0030712917876000003, B=210.0\right)$$
R210NO3 + O→NO2 + O2$$\mathrm{scaled_M}\left(A=0.006022140759999999\right)$$
R211NO + O→NO2$$\frac{3.263956139992805 \times 10^{-5} \cdot e^{0.0} \cdot \frac{300}{T}^{1.5} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.001806642228 \cdot \frac{300}{T}^{1.5} \cdot num_{density}\right)^{2}}} \cdot num_{density}^{2}}{1.0 + 0.001806642228 \cdot \frac{300}{T}^{1.5} \cdot num_{density}}$$
R212NO2 + O→NO3$$\mathrm{troe_M2_arr}\left(A=9.066544833313345 \times 10^{-5}, n_{inf}=1.8, k0_{300}=0.006843341772727273, n_{0}=1.1\right)$$
R213H2O2 + O→HO2 + OH$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=-2000.0\right)$$
R214H + O2→HO2$$\mathrm{troe_M2_arr}\left(A=1.5957118906631486 \times 10^{-5}, n_{inf}=1.3, k0_{300}=0.00035329892458666666, n_{0}=1.5\right)$$
R215O3 + H→OH + O2$$\mathrm{arrhenius_M}\left(A=0.08430997064000001, B=-470.0\right)$$
R216HO2 + H→2 OH$$\mathrm{scaled_M}\left(A=0.04335941347200001\right)$$
R217HO2 + H→H2O + O$$\mathrm{scaled_M}\left(A=0.0009635425216\right)$$
R218HO2 + H→O2 + H2$$\mathrm{scaled_M}\left(A=0.0041552771244000005\right)$$
R219N + O2→NO + O$$\mathrm{arrhenius_M}\left(A=0.00903321114, B=-3600.0\right)$$
R220NO + N→O + N2$$\mathrm{arrhenius_M}\left(A=0.012646495596, B=100.0\right)$$
R221N + NO2→N2O + O$$\mathrm{arrhenius_M}\left(A=0.0034928416408000003, B=220.0\right)$$
R222BrO + O→Br + O2$$\mathrm{arrhenius_M}\left(A=0.011442067443999998, B=230.0\right)$$
R223CH2O + O→CO + HO2 + OH$$\mathrm{arrhenius_M}\left(A=0.020475278584, B=-1600.0\right)$$
R224HCl + O1D→0.67 Cl + 0.24 ClO + 0.09 HCl + 0.67 OH + 0.24 H + 0.09 O$$\mathrm{scaled_M}\left(A=0.09033211140000001\right)$$
R225O1D + HBr→0.15 H + 0.15 BrO + 0.65 Br + 0.2 HBr + 0.65 OH + 0.2 O$$\mathrm{scaled_M}\left(A=0.09033211140000001\right)$$
R226O1D + Cl2→0.75 ClO + 0.25 Cl2 + 0.75 Cl + 0.25 O$$\mathrm{scaled_M}\left(A=0.16259780052000003\right)$$
R227CCl4 + O1D→0.86 ClO + 0.14 CCl4 + 2.58 Cl + 0.14 O$$\mathrm{scaled_M}\left(A=0.19873064508000002\right)$$
R228CH3Br + O1D→0.44 BrO + MO2 + 0.56 Br$$\mathrm{scaled_M}\left(A=0.10839853368000002\right)$$
R229O1D + CH2Br2→0.95 BrO + 0.95 Br + 0.05 CH2Br2 + 0.05 O$$\mathrm{scaled_M}\left(A=0.16259780052000003\right)$$
R230CHBr3 + O1D→0.68 BrO + 0.32 CHBr3 + 1.36 Br + 0.32 O$$\mathrm{scaled_M}\left(A=0.39746129016000004\right)$$
R231HCFC22 + O1D→0.28 HCFC22 + 0.55 ClO + 0.17 Cl + 0.28 O$$\mathrm{scaled_M}\left(A=0.061425835752\right)$$
R232CFC11 + O1D→0.12 CFC11 + 0.88 ClO + 1.76 Cl + 0.12 O$$\mathrm{scaled_M}\left(A=0.13850923748\right)$$
R233O1D + CFC12→0.86 Cl + 0.86 ClO + 0.14 CFC12 + 0.14 O$$\mathrm{scaled_M}\left(A=0.08430997064000001\right)$$
R234O1D + H1211→0.36 H1211 + 0.31 BrO + 0.33 Br + 0.33 ClO + 0.31 Cl + 0.36 O$$\mathrm{scaled_M}\left(A=0.09033211140000001\right)$$
R235H1301 + O1D→0.41 BrO + 0.59 H1301 + 0.59 O$$\mathrm{scaled_M}\left(A=0.060221407600000006\right)$$
R236HCFC141b + O1D→0.69 ClO + 0.31 HCFC141b + 0.69 Cl + 0.31 O$$\mathrm{scaled_M}\left(A=0.15657565976\right)$$
R237HCFC142b + O1D→0.26 HCFC142b + 0.74 ClO + 0.26 O$$\mathrm{scaled_M}\left(A=0.12044281520000001\right)$$
R238O1D + HCFC123→0.79 ClO + 0.21 HCFC123 + 0.79 Cl + 0.21 O$$\mathrm{scaled_M}\left(A=0.12044281520000001\right)$$
R239CFC113 + O1D→0.25 CFC113 + 0.75 ClO + 1.5 Cl + 0.25 O$$\mathrm{scaled_M}\left(A=0.139713665632\right)$$
R240CFC114 + O1D→0.25 CFC114 + 0.75 ClO + 0.75 Cl + 0.25 O$$\mathrm{arrhenius_M}\left(A=0.07828782987999999, B=-25.0\right)$$
R241O1D + CFC115→0.7 CFC115 + 0.3 ClO + 0.7 O$$\mathrm{arrhenius_M}\left(A=0.032519560104, B=-30.0\right)$$
R242O1D + H2402→0.75 BrO + 0.75 Br + 0.25 H2402 + 0.25 O$$0.09635425216 \cdot e^{0.0} \cdot num_{density}$$
R243OH + Cl2→HOCl + Cl$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=-1100.0\right)$$
R244MO2 + ClO→HO2 + CH2O + ClOO$$\mathrm{arrhenius_M}\left(A=0.010839853368, B=-600.0\right)$$
R245ClO + OH→HO2 + Cl$$\mathrm{arrhenius_M}\left(A=0.0044563841623999996, B=270.0\right)$$
R246ClO + OH→HCl + O2$$\mathrm{arrhenius_M}\left(A=0.0003613284456, B=230.0\right)$$
R247OClO + OH→HOCl + O2$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=600.0\right)$$
R248Cl2O2 + OH→HOCl + ClOO$$\mathrm{arrhenius_M}\left(A=0.0003613284456, B=670.0\right)$$
R249HCl + OH→H2O + Cl$$\mathrm{arrhenius_M}\left(A=0.0010839853368, B=-250.0\right)$$
R250HOCl + OH→ClO + H2O$$\mathrm{arrhenius_M}\left(A=0.0018066422280000002, B=-500.0\right)$$
R251ClNO2 + OH→HOCl + NO2$$\mathrm{arrhenius_M}\left(A=0.0014453137824, B=-1250.0\right)$$
R252ClNO3 + OH→HOCl + NO3$$\mathrm{arrhenius_M}\left(A=0.0007226568912, B=-330.0\right)$$
R253CH3Cl + OH→H2O + HO2 + Cl$$\mathrm{arrhenius_M}\left(A=0.00118033958896, B=-1200.0\right)$$
R254CH2Cl2 + OH→HO2 + 2 Cl$$\mathrm{arrhenius_M}\left(A=0.0015717787383600001, B=-944.0\right)$$
R255CHCl3 + OH→HO2 + 3 Cl$$\mathrm{arrhenius_M}\left(A=0.0028243840164399996, B=-1134.0\right)$$
R256CH3CCl3 + OH→H2O + 3 Cl$$\mathrm{arrhenius_M}\left(A=0.0009876310846400002, B=-1520.0\right)$$
R257HCFC22 + OH→H2O + Cl$$\mathrm{arrhenius_M}\left(A=0.0005540369499199999, B=-1560.0\right)$$
R258HCFC141b + OH→H2O + 2 Cl$$\mathrm{arrhenius_M}\left(A=0.000752767595, B=-1600.0\right)$$
R259HCFC142b + OH→H2O + Cl$$\mathrm{arrhenius_M}\left(A=0.0007828782988, B=-1770.0\right)$$
R260OH + HCFC123→H2O + 2 Cl$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=-900.0\right)$$
R261CH4 + Cl→MO2 + HCl$$\mathrm{arrhenius_M}\left(A=0.004275719939600001, B=-1270.0\right)$$
R262CH2O + Cl→CO + HCl + HO2$$\mathrm{arrhenius_M}\left(A=0.044082070363200006, B=-30.0\right)$$
R263O3 + Cl→ClO + O2$$\mathrm{arrhenius_M}\left(A=0.013850923748000002, B=-200.0\right)$$
R264Cl + H2→HCl + H$$\mathrm{arrhenius_M}\left(A=0.018367529318000002, B=-2270.0\right)$$
R265H2O2 + Cl→HCl + HO2$$\mathrm{arrhenius_M}\left(A=0.006624354836000001, B=-980.0\right)$$
R266HO2 + Cl→HCl + O2$$\mathrm{arrhenius_M}\left(A=0.008430997064, B=270.0\right)$$
R267HO2 + Cl→ClO + OH$$\mathrm{arrhenius_M}\left(A=0.021679706736, B=-375.0\right)$$
R268ClO + O→Cl + O2$$\mathrm{arrhenius_M}\left(A=0.016861994128, B=85.0\right)$$
R269ClO + HO2→HOCl + O2$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=290.0\right)$$
R270NO + ClO→NO2 + Cl$$\mathrm{arrhenius_M}\left(A=0.0038541700864, B=290.0\right)$$
R271ClO + NO2→ClNO3$$\mathrm{jpl_pdep_long}\left(A=6.527912279985607 \times 10^{-5}, Fc=0.6, k0_{300}=0.007226568912, n0=1.5, ninf=3.4\right)$$
R2722 ClO→Cl2 + O2$$\mathrm{arrhenius_M}\left(A=0.000602214076, B=-1590.0\right)$$
R2732 ClO→Cl + ClOO$$\mathrm{arrhenius_M}\left(A=0.01806642228, B=-2450.0\right)$$
R2742 ClO→OClO + Cl$$\mathrm{arrhenius_M}\left(A=0.00021077492660000001, B=-1370.0\right)$$
R275Cl + O2→ClOO$$\mathrm{jpl_pdep_long}\left(A=7.978559453315743 \times 10^{-7}, Fc=0.6, k0_{300}=7.360394262222223 \times 10^{-6}, n0=3.1, ninf=3.1\right)$$
R276ClOO→Cl + O2$$\frac{7.978559453315744 \times 10^{-7} \cdot e^{0} \cdot \frac{300}{T}^{3.1} \cdot num_{density} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(7.360394262222221 \times 10^{-6} \cdot \frac{300}{T}^{3.1} \cdot num_{density}\right)^{2}}}}{3.9746129016000004 \times 10^{-16} \cdot e^{\frac{2502.0}{T}} \cdot \left(1.0 + 7.360394262222221 \times 10^{-6} \cdot \frac{300}{T}^{3.1} \cdot num_{density}\right)}$$
R2772 ClO→Cl2O2$$\mathrm{jpl_pdep_long}\left(A=6.890574073318143 \times 10^{-6}, Fc=0.6, k0_{300}=0.003092450660540541, n0=2.0, ninf=3.6\right)$$
R278Cl2O2→2 ClO$$\frac{6.890574073318141 \times 10^{-6} \cdot e^{0} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.003092450660540541 \cdot \frac{300}{T}^{2.0} \cdot num_{density}\right)^{2}}} \cdot \frac{300}{T}^{3.6} \cdot num_{density}}{1.30078240416 \times 10^{-18} \cdot e^{\frac{8537.0}{T}} \cdot \left(1.0 + 0.003092450660540541 \cdot \frac{300}{T}^{2.0} \cdot num_{density}\right)}$$
R279Cl + ClOO→Cl2 + O2$$\mathrm{scaled_M}\left(A=0.13850923748\right)$$
R280Cl + ClOO→2 ClO$$\mathrm{scaled_M}\left(A=0.007226568912\right)$$
R281BrO + ClO→Br + OClO$$\mathrm{arrhenius_M}\left(A=0.0005721033722, B=550.0\right)$$
R282BrO + ClO→Br + ClOO$$\mathrm{arrhenius_M}\left(A=0.0013850923748, B=260.0\right)$$
R283BrO + ClO→BrCl + O2$$\mathrm{arrhenius_M}\left(A=0.00024690777116, B=290.0\right)$$
R284ClNO3 + O→ClO + NO3$$\mathrm{arrhenius_M}\left(A=0.0021679706736, B=-840.0\right)$$
R285ClNO3 + Cl→NO3 + Cl2$$\mathrm{arrhenius_M}\left(A=0.003914391494, B=135.0\right)$$
R286CH3Cl + Cl→CO + 2 HCl + HO2$$\mathrm{arrhenius_M}\left(A=0.0130680454492, B=-1130.0\right)$$
R287CH2Cl2 + Cl→CO + HCl + HO2 + 2 Cl$$\mathrm{arrhenius_M}\left(A=0.0007467454542399999, B=-1070.0\right)$$
R288CHCl3 + Cl→CO + HCl + HO2 + 3 Cl$$\mathrm{arrhenius_M}\left(A=0.0022703470665200003, B=-1011.0\right)$$
R289HCOOH + Cl→HCl + H2O + CO2$$\mathrm{scaled_M}\left(A=0.0001204428152\right)$$
R290MO2 + Cl→ClO + HO2 + CH2O$$\mathrm{scaled_M}\left(A=0.09635425215999999\right)$$
R291MP + Cl→MO2 + HCl$$\mathrm{scaled_M}\left(A=0.034326202332\right)$$
R292C2H6 + Cl→HCl + ETO2$$\mathrm{arrhenius_M}\left(A=0.043359413472, B=-70.0\right)$$
R293ETO2 + Cl→ALD2 + ClO + HO2$$\mathrm{scaled_M}\left(A=0.044563841624\right)$$
R294OTHRO2 + Cl→ALD2 + ClO + HO2$$\mathrm{scaled_M}\left(A=0.044563841624\right)$$
R295Cl + MOH→HCl + HO2 + CH2O$$\mathrm{scaled_M}\left(A=0.03312177418\right)$$
R296EOH + Cl→ALD2 + HCl$$\mathrm{scaled_M}\left(A=0.057812551296\right)$$
R297ACTA + Cl→MO2 + HCl + CO2$$\mathrm{scaled_M}\left(A=1.6861994128 \times 10^{-5}\right)$$
R298C3H8 + Cl→HCl + B3O2$$\mathrm{arrhenius_M}\left(A=0.0393848005704, B=60.0\right)$$
R299C3H8 + Cl→A3O2 + HCl$$\mathrm{arrhenius_M}\left(A=0.048899782971200005, B=-90.0\right)$$
R300ACET + Cl→HCl + ATO2$$\mathrm{arrhenius_M}\left(A=0.046370483852, B=-1000.0\right)$$
R301ISOP + Cl→0.5 IHOO4 + 0.5 IHOO1 + HCl$$\mathrm{arrhenius_M}\left(A=0.045768269776, B=500.0\right)$$
R302ALK4 + Cl→HCl + R4O2$$\mathrm{scaled_M}\left(A=0.12345388557999999\right)$$
R303PRPE + Cl→PO2 + HCl$$\frac{0.14506471733301352 \cdot e^{0.0} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(0.8603058228571426 \cdot num_{density}\right)^{2}}} \cdot num_{density}^{2}}{1.0 + 0.8603058228571426 \cdot num_{density}}$$
R304Br + PRPE→PO2 + HBr$$\mathrm{scaled_M}\left(A=0.0021679706736\right)$$
R305NO + I→INO$$\frac{0.0019583736839956824 \cdot e^{0.0} \cdot 0.6^{\frac{1.0}{1.0 + \log_{10}\left(\frac{3.2519560104 \times 10^{-18} \cdot num_{density}}{1.77 \times 10^{-17} \cdot T}\right)^{2}}} \cdot num_{density}^{2}}{T \cdot \left(1.0 + \frac{3.2519560104 \times 10^{-18} \cdot num_{density}}{1.77 \times 10^{-17} \cdot T}\right)}$$
R3062 INO→2 NO + I2$$\mathrm{arrhenius_M}\left(A=0.050585982384, B=-2620.0\right)$$
R307I + NO2→IONO$$\frac{0.03263956139992803 \cdot e^{0.0} \cdot 0.63^{\frac{1.0}{1.0 + \log_{10}\left(\frac{5.419926684 \times 10^{-17} \cdot num_{density}}{6.6 \times 10^{-17} \cdot T}\right)^{2}}} \cdot num_{density}^{2}}{T \cdot \left(1.0 + \frac{5.419926684 \times 10^{-17} \cdot num_{density}}{6.6 \times 10^{-17} \cdot T}\right)}$$
R308IONO→I + NO2$$\mathrm{arrhenius}\left(A=9.94 \times 10^{17}, B=-11859.0\right)$$
R3092 IONO→I2 + 2 NO2$$\mathrm{arrhenius_M}\left(A=0.017464208204, B=-2600.0\right)$$
R310I2 + NO3→IONO2 + I$$\mathrm{scaled_M}\left(A=0.000903321114\right)$$
R311IO + NO2→IONO2$$\mathrm{jpl_pdep_long}\left(A=0.0002719963449994003, Fc=0.6, k0_{300}=0.05942902065789474, n0=2.0, ninf=3.5\right)$$
R312IONO2→IO + NO2$$\mathrm{arrhenius}\left(A=2100000000000000.0, B=-13670.0\right)$$
R313IONO2 + I→I2 + NO3$$\mathrm{arrhenius_M}\left(A=0.054801480916000005, B=-146.0\right)$$
R314BrO + I→IO + Br$$\mathrm{scaled_M}\left(A=0.007226568912\right)$$
R315BrO + IO→I + Br + O2$$\mathrm{arrhenius_M}\left(A=0.0018066422280000002, B=510.0\right)$$
R316BrO + IO→Br + OIO$$\mathrm{arrhenius_M}\left(A=0.007226568912000001, B=510.0\right)$$
R317IO + OIO→I2O3$$\mathrm{scaled_M}\left(A=0.060221407600000006\right)$$
R3182 OIO→I2O4$$\mathrm{scaled_M}\left(A=0.09033211140000001\right)$$
R319I2O4→2 OIO$$0.038$$
R320NO + OIO→IO + NO2$$\mathrm{arrhenius_M}\left(A=0.0006624354836000001, B=542.0\right)$$
R321IO + ClO→I + OClO$$\mathrm{arrhenius_M}\left(A=0.0030712917876, B=280.0\right)$$
R322IO + ClO→I + Cl + O2$$\mathrm{arrhenius_M}\left(A=0.00169222155356, B=280.0\right)$$
R323IO + ClO→ICl + O2$$\mathrm{arrhenius_M}\left(A=0.0006142583575200002, B=280.0\right)$$
R324I + O3→IO + O2$$\mathrm{arrhenius_M}\left(A=0.013850923748000002, B=-870.0\right)$$
R325I + HO2→O2 + HI$$\mathrm{arrhenius_M}\left(A=0.00903321114, B=-1090.0\right)$$
R326I2 + OH→HOI + I$$\mathrm{scaled_M}\left(A=0.10839853368000002\right)$$
R327OH + HI→I + H2O$$\mathrm{scaled_M}\left(A=0.01806642228\right)$$
R328HOI + OH→IO + H2O$$\mathrm{scaled_M}\left(A=0.0030110703799999996\right)$$
R329IO + HO2→HOI + O2$$\mathrm{arrhenius_M}\left(A=0.007828782988, B=570.0\right)$$
R330NO + IO→I + NO2$$\mathrm{arrhenius_M}\left(A=0.0054801480916, B=240.0\right)$$
R3312 IO→I + OIO$$\mathrm{arrhenius_M}\left(A=0.0036132844560000004, B=500.0\right)$$
R3322 IO→I2O2$$\mathrm{arrhenius_M}\left(A=0.005419926684, B=500.0\right)$$
R333I2O2→2 IO$$\mathrm{arrhenius}\left(A=1000000000000.0, B=-9770.0\right)$$
R334I2O2→I + OIO$$\mathrm{arrhenius}\left(A=250000000000000.0, B=-9770.0\right)$$
R335OH + CH3I→I + MO2 + H2O$$\mathrm{arrhenius_M}\left(A=0.0017464208204000002, B=-1100.0\right)$$
R336OH + ETHLN→NO2 + CO2 + CH2O$$\mathrm{scaled_M}\left(A=0.0014453137824\right)$$
R337PROPNN + OH→NO2 + MGLY$$\mathrm{scaled_M}\left(A=0.00040348343092000004\right)$$
R338CO + CH2OO→CH2O$$\mathrm{scaled_M}\left(A=7.226568911999999 \times 10^{-7}\right)$$
R339NO + CH2OO→NO2 + CH2O$$\mathrm{scaled_M}\left(A=6.022140760000001 \times 10^{-6}\right)$$
R340CH2OO + NO2→NO3 + CH2O$$\mathrm{scaled_M}\left(A=6.022140760000001 \times 10^{-7}\right)$$
R341CH2OO + H2O→0.73 HMHP + 0.06 H2O2 + 0.21 HCOOH + 0.06 CH2O$$\mathrm{scaled_M}\left(A=1.0237639292 \times 10^{-6}\right)$$
R342CH2OO + 2 H2O→0.4 HMHP + 0.06 H2O2 + 0.54 HCOOH + 0.06 CH2O$$1.0444659647976974 \times 10^{-17} \cdot num_{density}^{2} \cdot e^{\frac{1391.0}{T}}$$
R343O3 + CH2OO→CH2O$$\mathrm{scaled_M}\left(A=0.0008430997064000001\right)$$
R344CH2OO + SO2→SO4 + CH2O$$\mathrm{scaled_M}\left(A=0.022281920812\right)$$
R345CO + CH3CHOO→ALD2$$\mathrm{scaled_M}\left(A=7.226568911999999 \times 10^{-7}\right)$$
R346NO + CH3CHOO→ALD2 + NO2$$\mathrm{scaled_M}\left(A=6.022140760000001 \times 10^{-6}\right)$$
R347CH3CHOO + NO2→ALD2 + NO3$$\mathrm{scaled_M}\left(A=6.022140760000001 \times 10^{-7}\right)$$
R348CH3CHOO + SO2→ALD2 + SO4$$\mathrm{scaled_M}\left(A=4.2154985320000006 \times 10^{-5}\right)$$
R349CH3CHOO + H2O→ALD2 + H2O2$$\mathrm{scaled_M}\left(A=3.613284456 \times 10^{-9}\right)$$
R350CH3CHOO + H2O→ACTA$$\mathrm{scaled_M}\left(A=6.022140760000001 \times 10^{-9}\right)$$
R351MTPA + OH→PIO2$$\mathrm{arrhenius_M}\left(A=0.0072867903196000006, B=440.0\right)$$
R352MTPO + OH→PIO2$$\mathrm{arrhenius_M}\left(A=0.0072867903196000006, B=440.0\right)$$
R353PIO2 + NO→0.06 MONITU + 0.11 ACET + 0.43 RCHO + 0.44 MEK + 0.12 MONITS + 0.82 NO2 + 0.82 HO2 + 0.07 HCOOH + 0.23 CH2O$$\mathrm{scaled_M}\left(A=0.002408856304\right)$$
R354PIO2 + HO2→PIP$$\mathrm{scaled_M}\left(A=0.00903321114\right)$$
R355PIO2 + MO2→0.75 MEK + 0.75 RCHO + 0.25 ROH + HO2 + 0.75 CH2O + 0.25 MOH$$\mathrm{arrhenius_M}\left(A=2.14388211056 \times 10^{-5}, B=708.0\right)$$
R356PIO2 + MCO3→RCOOH + 0.5 MO2 + RCHO + MEK + 0.5 HO2$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=765.0\right)$$
R357PIO2 + NO3→MEK + RCHO + NO2 + HO2$$\mathrm{scaled_M}\left(A=0.0007226568912\right)$$
R358MTPA + O3→0.62 KO2 + 0.14 CO + 0.53 MEK + 0.65 RCHO + 0.1 HO2 + 0.02 H2O2 + 0.85 OH$$\mathrm{arrhenius_M}\left(A=3.0110703800000003 \times 10^{-7}, B=-530.0\right)$$
R359O3 + MTPO→0.62 KO2 + 0.14 CO + 0.53 MEK + 0.65 RCHO + 0.1 HO2 + 0.02 H2O2 + 0.85 OH$$\mathrm{arrhenius_M}\left(A=3.0110703800000003 \times 10^{-7}, B=-530.0\right)$$
R360MTPA + NO3→0.1 OLNN + 0.9 OLND$$\mathrm{arrhenius_M}\left(A=0.000501644325308, B=490.0\right)$$
R361NO3 + MTPO→0.1 OLNN + 0.9 OLND$$\mathrm{arrhenius_M}\left(A=0.000501644325308, B=490.0\right)$$
R362LIMO + OH→LIMO2$$\mathrm{arrhenius_M}\left(A=0.025292991192, B=401.0\right)$$
R363O3 + LIMO→0.42 KO2 + 0.79 MACR + 0.14 CO + 0.1 HO2 + 0.85 OH + 0.16 OTHRO2 + 0.07 RCOOH + 0.46 PRPE + 0.02 H2O2 + 0.01 HCOOH + 0.04 CH2O$$\mathrm{arrhenius_M}\left(A=1.7765315242 \times 10^{-6}, B=-783.0\right)$$
R364NO3 + LIMO→0.5 OLNN + 0.5 OLND$$\mathrm{scaled_M}\left(A=0.0073470117272\right)$$
R365NO + LIMO2→0.22 MONITU + 0.289 MEK + 0.491 RCHO + 0.289 PRPE + 0.78 NO2 + 0.686 HO2 + 0.231 CH2O + 0.058 HAC$$\mathrm{scaled_M}\left(A=0.002408856304\right)$$
R366LIMO2 + HO2→PIP$$\mathrm{scaled_M}\left(A=0.00903321114\right)$$
R367MO2 + LIMO2→0.192 PRPE + 0.25 ROH + HO2 + 0.308 MACR + 1.04 CH2O + 0.25 MOH$$\mathrm{arrhenius_M}\left(A=2.14388211056 \times 10^{-5}, B=708.0\right)$$
R368MCO3 + LIMO2→0.5 RCOOH + 0.5 MO2 + 0.192 PRPE + 0.5 HO2 + 0.308 MACR + 0.385 CH2O$$\mathrm{arrhenius_M}\left(A=0.00044563841624, B=765.0\right)$$
R369NO3 + LIMO2→0.385 PRPE + NO2 + HO2 + 0.615 MACR + 0.385 CH2O$$\mathrm{scaled_M}\left(A=0.0007226568912\right)$$
R370PIP + OH→0.41 MEK + 0.08 RCHO + 0.44 R4O2 + 0.49 OH$$\mathrm{arrhenius_M}\left(A=0.0020475278584, B=190.0\right)$$
R371NO + OLNN→MONITS + NO2 + HO2$$\mathrm{scaled_M}\left(A=0.002408856304\right)$$
R372NO + OLND→0.464 MEK + 1.24 RCHO + 2 NO2 + 0.287 CH2O$$\mathrm{scaled_M}\left(A=0.002408856304\right)$$
R373OLNN + HO2→0.3 MONITU + 0.7 MONITS$$\mathrm{arrhenius_M}\left(A=9.9967536616 \times 10^{-5}, B=1300.0\right)$$
R374OLND + HO2→0.3 MONITU + 0.7 MONITS$$\mathrm{arrhenius_M}\left(A=9.9967536616 \times 10^{-5}, B=1300.0\right)$$
R375MO2 + OLNN→0.3 MONITU + 0.7 MONITS + 2 HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=9.635425216 \times 10^{-5}, B=708.0\right)$$
R376MO2 + OLND→0.15 MONITU + 0.348 MEK + 0.93 RCHO + 0.25 ROH + 0.35 MONITS + 0.5 NO2 + 0.5 HO2 + 0.965 CH2O + 0.25 MOH$$\mathrm{arrhenius_M}\left(A=5.8294322556800003 \times 10^{-5}, B=708.0\right)$$
R377MCO3 + OLNN→0.3 MONITU + MO2 + 0.7 MONITS + HO2$$\mathrm{arrhenius_M}\left(A=0.00053295945726, B=765.0\right)$$
R378MCO3 + OLND→0.5 RCOOH + 0.5 MO2 + 1.24 RCHO + 0.464 MEK + NO2 + 0.287 CH2O$$\mathrm{arrhenius_M}\left(A=0.00032338895881200004, B=765.0\right)$$
R379OLNN + NO3→0.3 MONITU + 0.7 MONITS + NO2 + HO2$$\mathrm{scaled_M}\left(A=0.0007226568912\right)$$
R380NO3 + OLND→0.464 MEK + 1.24 RCHO + 2 NO2 + 0.287 CH2O$$\mathrm{scaled_M}\left(A=0.0007226568912\right)$$
R3812 OLNN→0.6 MONITU + 1.4 MONITS + HO2$$\mathrm{arrhenius_M}\left(A=4.2154985320000006 \times 10^{-5}, B=1000.0\right)$$
R382OLNN + OLND→0.45 MONITU + 0.149 MEK + 0.64 RCHO + 1.05 MONITS + 0.5 NO2 + 0.5 HO2 + 0.202 CH2O$$\mathrm{arrhenius_M}\left(A=2.559409823 \times 10^{-5}, B=1000.0\right)$$
R3832 OLND→0.3 MONITU + 0.285 MEK + 1.21 RCHO + 0.7 MONITS + NO2 + 0.504 CH2O$$\mathrm{arrhenius_M}\left(A=1.7825536649600002 \times 10^{-5}, B=1000.0\right)$$
R384MONITS + OH→HONIT$$\mathrm{scaled_M}\left(A=0.0028906275648\right)$$
R385MONITU + OH→HONIT$$\mathrm{scaled_M}\left(A=0.0439014061404\right)$$
R386MONITU + O3→HONIT$$\mathrm{scaled_M}\left(A=1.00569750692 \times 10^{-7}\right)$$
R387MONITU + NO3→HONIT$$\mathrm{arrhenius_M}\left(A=0.00018969743394000002, B=-448.0\right)$$
R388MONITS + NO3→HONIT$$\mathrm{arrhenius_M}\left(A=0.00018969743394000002, B=-448.0\right)$$
R389IONITA→HNO3 + INDIOL$$0.000278$$
R390MONITA→HNO3 + INDIOL$$0.000278$$
R391HONIT + OH→NO3 + HAC$$\frac{2.3609282745947946 \times 10^{-7} \cdot num_{density}^{2} \cdot e^{\frac{1335.0}{T}}}{1.0 + \frac{3.9204136347599994 \times 10^{-22} \cdot num_{density} \cdot e^{\frac{1335.0}{T}}}{2.69 \times 10^{-23} \cdot e^{\frac{2199.0}{T}}}} + 1.4513359231599999 \times 10^{-5} \cdot e^{\frac{460.0}{T}} \cdot num_{density}$$
R392MENO3 + OH→NO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0004817712608, B=-1000.0\right)$$
R393ETNO3 + OH→ALD2 + NO2$$\mathrm{arrhenius_M}\left(A=0.000602214076, B=-490.0\right)$$
R394IPRNO3 + OH→ACET + NO2$$\mathrm{arrhenius_M}\left(A=0.0007226568912, B=-320.0\right)$$
R395NPRNO3 + OH→RCHO + NO2$$\mathrm{scaled_M}\left(A=0.00042757199396000004\right)$$
R396O3 + ISOP→0.013 H2O2 + 0.177 MVK + 0.407 CO + 0.407 MO2 + 0.58 CH2OO + 0.16 HO2 + 0.416 MACR + 0.28 OH + 0.407 CO2 + 0.827 CH2O$$\mathrm{scaled_M}\left(A=7.828782988 \times 10^{-9}\right)$$
R397ISOP + OH→IHOO1 + LISOPOH$$0.010237639292 \cdot \left(1.0 + \frac{\left(-471165000000000.0\right) \cdot e^{\frac{-12200.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}}}{179000000000000.0 \cdot e^{\frac{-8830.0}{T}} + 5050000000000000.0 \cdot e^{\frac{-12200.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}}}\right) \cdot num_{density} \cdot e^{\frac{390.0}{T}}$$
R398ISOP + OH→IHOO4 + LISOPOH$$0.00602214076 \cdot \left(1.0 + \frac{\left(-501720000.0\right) \cdot e^{\frac{-7160.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}}}{175000000000000.0 \cdot e^{\frac{-9054.0}{T}} + 2220000000.0 \cdot e^{\frac{-7160.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}}}\right) \cdot num_{density} \cdot e^{\frac{390.0}{T}}$$
R399ISOP + OH→0.6 CO + 0.3 MCO3 + 0.25 HPALD1 + 0.3 HPETHNL + 0.3 MGLY + 0.4 HO2 + LISOPOH + 0.15 HPALD3 + 0.3 CH2O + 1.5 OH$$\frac{4823617317015.18 \cdot e^{\frac{-12200.0}{T}} \cdot e^{\frac{390.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}} \cdot num_{density}}{179000000000000.0 \cdot e^{\frac{-8830.0}{T}} + 5050000000000000.0 \cdot e^{\frac{-12200.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}}}$$
R400ISOP + OH→0.15 HPALD4 + 0.9 CO + 0.25 HPALD2 + 0.3 ATOOH + 0.3 MGLY + 0.7 HO2 + LISOPOH + 1.5 OH + 0.3 CH2O$$\frac{3021428.4621072 \cdot e^{\frac{-7160.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}} \cdot e^{\frac{390.0}{T}} \cdot num_{density}}{175000000000000.0 \cdot e^{\frac{-9054.0}{T}} + 2220000000.0 \cdot e^{\frac{-7160.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}}}$$
R401IHOO1 + HO2→0.937 RIPA + 0.063 MVK + 0.063 HO2 + 0.063 OH + 0.063 CH2O$$\mathrm{arrhenius_clamp_lin}\left(B=1.1644, C=-0.00070485\right)$$
R402IHOO1 + HO2→RIPC$$\mathrm{arrhenius_clamp_lin}\left(B=-0.1644, C=0.00070485\right)$$
R403IHOO4 + HO2→0.063 HO2 + 0.063 MACR + 0.063 OH + 0.063 CH2O + 0.937 RIPB$$\mathrm{arrhenius_clamp_lin}\left(B=1.2038, C=-0.00090435\right)$$
R404IHOO4 + HO2→RIPD$$\mathrm{arrhenius_clamp_lin}\left(B=-0.2038, C=0.00090435\right)$$
R405IHOO1→MVK + OH + CH2O$$\frac{104000000000.0 \cdot \left(1.1644 + \left(-0.00070485\right) \cdot T\right) \cdot e^{\frac{-9746.0}{T}} + \left
R406IHOO1→0.6 CO + 0.3 MCO3 + 0.25 HPALD1 + 0.3 HPETHNL + 0.3 MGLY + 0.4 HO2 + 0.15 HPALD3 + 1.5 OH + 0.3 CH2O$$\frac{5050000000000000.0 \cdot e^{\frac{100000000.0}{T^{3}}} \cdot e^{\frac{-12200.0}{T}} \cdot \left(-0.0128 + 5.1242 \times 10^{-5} \cdot T\right) + \left
R407IHOO4→MACR + OH + CH2O$$\frac{188000000000.0 \cdot \left(1.2038 + \left(-0.00090435\right) \cdot T\right) \cdot e^{\frac{-9752.0}{T}} + \left
R408IHOO4→0.15 HPALD4 + 0.9 CO + 0.25 HPALD2 + 0.3 ATOOH + 0.3 MGLY + 0.7 HO2 + 1.5 OH + 0.3 CH2O$$\frac{2220000000.0 \cdot \left(-0.0306 + 0.00011346 \cdot T\right) \cdot e^{\frac{-7160.0}{T}} \cdot e^{\frac{100000000.0}{T^{3}}} + \left
R4092 IHOO1→2 MVK + 2 HO2 + 2 CH2O$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=4.16732140592 \times 10^{-5}, B=1.1644, C=-0.00070485\right)$$
R4102 IHOO4→2 HO2 + 2 MACR + 2 CH2O$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.0034567087962400003, B=1.2038, C=-0.00090435\right)$$
R411IHOO4 + IHOO1→MVK + 2 HO2 + MACR + 2 CH2O$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.0009274096770399999, B=2.3682, C=-0.0016092\right)$$
R4122 IHOO1→CO + MVKHP + HO2 + HC5A + OH$$\frac{0.0014995130492400002 \cdot e^{0} \cdot \left(-0.1644 + 0.00070485 \cdot T\right) \cdot num_{density} + \left
R4132 IHOO4→CO + HO2 + HC5A + OH + MCRHP$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.00237272345944, B=-0.2038, C=0.00090435\right)$$
R414IHOO4 + IHOO1→CO + 0.5 MVKHP + HO2 + HC5A + OH + 0.5 MCRHP$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.00092740967704, B=-0.3682, C=0.0016092\right)$$
R415MO2 + IHOO1→MVK + 2 HO2 + 2 CH2O$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.001204428152, B=1.1644, C=-0.00070485\right)$$
R416MO2 + IHOO1→0.5 CO + 0.5 MVKHP + 1.5 HO2 + 0.5 HC5A + 0.5 OH + CH2O$$\frac{0.001204428152 \cdot e^{0} \cdot \left(-0.1644 + 0.00070485 \cdot T\right) \cdot num_{density} + \left
R417IHOO4 + MO2→2 HO2 + MACR + 2 CH2O$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.001204428152, B=1.2038, C=-0.00090435\right)$$
R418IHOO4 + MO2→0.5 CO + 1.5 HO2 + 0.5 HC5A + 0.5 OH + CH2O + 0.5 MCRHP$$\mathrm{arrhenius_clamp_M_lin_exp0}\left(A=0.001204428152, B=-0.2038, C=0.00090435\right)$$
R419NO + IHOO1→IHN2$$\frac{\frac{7.90064332542301 \times 10^{-5} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot \left(1.1644 + \left(-0.000705\right) \cdot T\right) \cdot num_{density}^{2}}{\left(1.19 + \frac{0.04859009962100446 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R420NO + IHOO1→MVK + NO2 + HO2 + CH2O$$\frac{\frac{0.001934913826188 \cdot e^{\frac{350.0}{T}} \cdot \left(1.1644 + \left(-0.000705\right) \cdot T\right) \cdot num_{density}}{1.19 + \frac{0.04859009962100446 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}}}{1.0 + 0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left
R421NO + IHOO1→IHN4$$\frac{\frac{7.90064332542301 \times 10^{-5} \cdot \left(-0.1644 + 0.000705 \cdot T\right) \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2}}{\left(1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right) \cdot \left(1.421 + \frac{0.04859009962100446 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right)} + \left
R422NO + IHOO1→0.55 CO + 0.55 MVKHP + NO2 + 0.45 HO2 + 0.45 HC5A + 0.55 OH$$\frac{\frac{0.0023105147453892 \cdot \left(-0.1644 + 0.000705 \cdot T\right) \cdot e^{\frac{350.0}{T}} \cdot num_{density}}{1.421 + \frac{0.04859009962100446 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}}}{1.0 + 0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left
R423NO + IHOO4→IHN3$$\frac{\frac{7.90064332542301 \times 10^{-5} \cdot \left(1.2038 + \left(-0.000904\right) \cdot T\right) \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2}}{\left(1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right) \cdot \left(1.297 + \frac{0.04859009962100446 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right)} + \left
R424NO + IHOO4→NO2 + HO2 + MACR + CH2O$$\frac{\frac{0.0021088934727443998 \cdot \left(1.2038 + \left(-0.000904\right) \cdot T\right) \cdot e^{\frac{350.0}{T}} \cdot num_{density}}{1.297 + \frac{0.04859009962100446 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}}}{1.0 + 0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left
R425NO + IHOO4→IHN1$$\frac{\frac{7.90064332542301 \times 10^{-5} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2} \cdot \left(-0.2038 + 0.000904 \cdot T\right)}{\left(1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right) \cdot \left(1.421 + \frac{0.04859009962100446 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.04859009962100446 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right)} + \left
R426NO + IHOO4→0.55 CO + NO2 + 0.45 HO2 + 0.45 HC5A + 0.55 OH + 0.55 MCRHP$$\frac{\frac{0.0023105147453892 \cdot e^{\frac{350.0}{T}} \cdot num_{density} \cdot \left(-0.2038 + 0.000904 \cdot T\right)}{1.421 + \frac{0.04859009962100446 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}}}{1.0 + 0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left
R427HPALD1 + OH→0.035 MVK + 0.45 CO + 0.33 MVKHP + 0.085 ICHE + 0.315 HPALD1OO + 0.085 MGLY + 0.085 HO2 + 1.085 OH + 0.085 CH2O + 0.15 IDC$$\mathrm{arrhenius_M}\left(A=0.007045904689200001, B=450.0\right)$$
R428HPALD2 + OH→0.165 CH2O + 0.37 CO + 0.165 ICHE + 0.315 HPALD2OO + 0.165 MGLY + 0.165 HO2 + 0.035 MACR + 1.165 OH + 0.17 MCRHP + 0.15 IDC$$\mathrm{arrhenius_M}\left(A=0.007045904689200001, B=450.0\right)$$
R429HPALD3 + OH→0.23 MVK + 0.42 CO + 0.19 MVKHP + 0.58 ICHE + OH$$\mathrm{arrhenius_M}\left(A=0.013248709672000002, B=390.0\right)$$
R430HPALD4 + OH→0.23 CO + 0.77 ICHE + 0.14 MACR + OH + 0.09 MCRHP$$\mathrm{arrhenius_M}\left(A=0.021077492660000002, B=390.0\right)$$
R431HC5A + OH→0.638 CO + 0.125 MVKHP + 0.068 IEPOXBOO + 0.355 MGLY + 0.283 HO2 + 0.355 CO2 + 1.065 OH + 0.294 IEPOXAOO + 0.158 MCRHP$$\mathrm{arrhenius_M}\left(A=0.0027942733126399997, B=650.0\right)$$
R432ICHE + OH→1.5 CO + 0.5 MGLY + OH + 0.5 CH2O + 0.5 HAC$$\mathrm{arrhenius_M}\left(A=0.0059318086486, B=410.0\right)$$
R433OH + IDC→MVKPC + CO + HO2$$\mathrm{arrhenius_M}\left(A=0.0018066422280000002, B=650.0\right)$$
R434RIPA + OH→0.345 IHPOO1 + 0.655 IHPOO3 + 0.005 LVOC$$\mathrm{arrhenius_M}\left(A=0.0014874687677200002, B=390.0\right)$$
R435RIPA + OH→0.33 IEPOXB + 0.005 LVOC + OH + 0.67 IEPOXA$$\mathrm{arrhenius_M_div_lin}\left(A=0.0097558680312, B=390.0, C=0.00287256114252\right)$$
R436OH + RIPB→0.345 IHPOO2 + 0.655 IHPOO3 + 0.005 LVOC$$\mathrm{arrhenius_M}\left(A=0.0026196312306, B=390.0\right)$$
R437OH + RIPB→0.32 IEPOXB + 0.005 LVOC + OH + 0.68 IEPOXA$$\mathrm{arrhenius_M_div_lin}\left(A=0.017163101166, B=390.0, C=0.00287256114252\right)$$
R438RIPA + OH→0.125 MVK + 0.25 CO + 0.125 MVKHP + 0.75 IHOO1 + 0.25 HO2 + 0.005 LVOC$$\mathrm{arrhenius_M}\left(A=0.0036735058636000006, B=200.0\right)$$
R439OH + RIPB→0.33 CO + 0.51 IHOO4 + 0.16 ICHOO + 0.33 HO2 + 0.165 MACR + 0.005 LVOC + 0.165 MCRHP$$\mathrm{arrhenius_M}\left(A=0.0024690777116, B=200.0\right)$$
R440RIPC + OH→0.018 HPETHNL + 0.005 LVOC + 0.06 HC5A + 0.595 IHPOO1 + 0.015 HPALD1 + 0.009 HPALD3 + 0.036 CO + 0.255 IEPOXD + 0.024 HO2 + 0.405 OH + 0.018 MCO3 + 0.03 IHOO1 + 0.018 MGLY + 0.018 CH2O$$\mathrm{arrhenius_M}\left(A=0.0212581568828, B=390.0\right)$$
R441RIPD + OH→0.255 IHPOO2 + 0.015 HPALD2 + 0.005 LVOC + 0.06 HC5A + 0.054 CO + 0.018 ATOOH + 0.595 IEPOXD + 0.042 HO2 + 0.745 OH + 0.009 HPALD4 + 0.03 IHOO4 + 0.018 MGLY + 0.018 CH2O$$\mathrm{arrhenius_M}\left(A=0.0212581568828, B=390.0\right)$$
R442IHPOO1→0.176 ICPDH + 0.824 IDHPE + OH$$\mathrm{arrhenius}\left(A=15900000000000.0, B=-10000.0\right)$$
R443IHPOO1 + NO→0.284 HAC + 0.284 HPETHNL + NO2 + HO2 + 0.716 MCRHP + 0.716 CH2O$$\mathrm{troe_clamp_arr_M}\left(A=0.0034145538109200003, B=2.1, Fc=0.9759582400390522, M0=2.2696703256722146\right)$$
R444IHPOO1 + NO→ITHN$$\mathrm{troe_clamp_jpl_alt}\left(A=0.0015868866322972007, Fc=0.9759582400390522, B=2.1\right)$$
R445IHPOO1 + HO2→0.135 HAC + 0.725 IDHDP + 0.135 HPETHNL + 0.275 HO2 + 0.275 OH + 0.14 MCRHP + 0.14 CH2O$$\mathrm{arrhenius_M}\left(A=0.000148746876772, B=1300.0\right)$$
R446IHPOO2→0.548 ICPDH + 0.452 IDHPE + OH$$\mathrm{arrhenius}\left(A=29100000000000.0, B=-10000.0\right)$$
R447NO + IHPOO2→0.706 MVKHP + 0.294 ATOOH + 0.294 GLYC + NO2 + HO2 + 0.706 CH2O$$\mathrm{troe_clamp_arr_M}\left(A=0.0037641390820379998, B=2.315, Fc=0.9759582400390522, M0=2.2696703256722146\right)$$
R448NO + IHPOO2→ITHN$$\frac{\frac{0.0015868866322972007 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.9759582400390522 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2}}{\left(1.0 + \frac{0.9759582400390522 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right) \cdot \left(2.315 + \frac{0.9759582400390522 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.9759582400390522 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{0.9759582400390522 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right)} + \left
R449IHPOO2 + HO2→0.14 MVKHP + 0.135 ATOOH + 0.725 IDHDP + 0.135 GLYC + 0.275 HO2 + 0.275 OH + 0.14 CH2O$$\mathrm{arrhenius_M}\left(A=0.000148746876772, B=1300.0\right)$$
R450IHPOO3→IDHPE$$\mathrm{arrhenius}\left(A=18750000000000.0, B=-10000.0\right)$$
R451NO + IHPOO3→GLYC + NO2 + OH + HAC$$\mathrm{troe_clamp_arr_M}\left(A=0.0050063862780108, B=3.079, Fc=0.9759582400390522, M0=2.2696703256722146\right)$$
R452NO + IHPOO3→ITHN$$\mathrm{troe_clamp_jpl_alt}\left(A=0.0015868866322972007, Fc=0.9759582400390522, B=3.079\right)$$
R453IHPOO3 + HO2→0.35 IDHDP + 0.65 GLYC + 1.3 OH + 0.65 HAC$$\mathrm{arrhenius_M}\left(A=0.00014874687677200003, B=1300.0\right)$$
R454IEPOXD + OH→0.25 ICHOO + 0.75 ICHE + 0.75 HO2$$\mathrm{arrhenius_M}\left(A=0.019391293247200004, B=-400.0\right)$$
R455OH + IEPOXA→ICHE + HO2$$\mathrm{arrhenius_M}\left(A=0.006323247798, B=-400.0\right)$$
R456OH + IEPOXA→0.33 IEPOXBOO + 0.67 IEPOXAOO$$\mathrm{arrhenius_M_div_lin}\left(A=0.0350488592232, B=-400.0, C=0.006865240466399999\right)$$
R457IEPOXB + OH→ICHE + HO2$$\mathrm{arrhenius_M}\left(A=0.004968266127000001, B=-400.0\right)$$
R458IEPOXB + OH→0.19 IEPOXBOO + 0.81 IEPOXAOO$$\mathrm{arrhenius_M_div_lin}\left(A=0.02258302785, B=-400.0, C=0.00536572741716\right)$$
R459IEPOXAOO→IDCHP + HO2$$\mathrm{arrhenius}\left(A=18750000000000.0, B=-10000.0\right)$$
R460IEPOXAOO→CO + MVKDH + OH$$\mathrm{arrhenius}\left(A=10000000.0, B=-5000.0\right)$$
R461HO2 + IEPOXAOO→0.13 CO + 0.35 ICPDH + 0.13 MVKDH + 0.52 GLYC + 0.52 MGLY + 0.65 HO2 + 0.65 OH$$\mathrm{arrhenius_M}\left(A=0.000143326950088, B=1300.0\right)$$
R462NO + IEPOXAOO→0.2 CO + 0.2 MVKDH + 0.8 GLYC + NO2 + 0.8 MGLY + HO2$$\mathrm{troe_clamp_arr_M}\left(A=0.0212970599121096, B=13.098, Fc=0.3590349719522309, M0=0.8349650510516997\right)$$
R463NO + IEPOXAOO→ITCN$$\frac{\frac{0.0005837829674919263 \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}}}{\left(13.098 + \frac{0.3590349719522309 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}}}{1.0 + \frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R464IEPOXBOO→IDCHP + HO2$$\mathrm{arrhenius}\left(A=18750000000000.0, B=-10000.0\right)$$
R465IEPOXBOO→MCRDH + CO + OH$$\mathrm{arrhenius}\left(A=10000000.0, B=-5000.0\right)$$
R466NO + IEPOXBOO→0.8 GLYX + 0.2 CO + 0.2 MCRDH + NO2 + HO2 + 0.8 HAC$$\mathrm{troe_clamp_arr_M}\left(A=0.026768475899607597, B=16.463, Fc=0.3590349719522309, M0=0.8349650510516997\right)$$
R467NO + IEPOXBOO→ITCN$$\frac{\frac{0.0005837829674919263 \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}}}{\left(16.463 + \frac{0.3590349719522309 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}}}{1.0 + \frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R468IEPOXBOO + HO2→0.13 MCRDH + 0.13 CO + 0.52 GLYX + 0.35 ICPDH + 0.65 HO2 + 0.65 OH + 0.52 HAC$$\mathrm{arrhenius_M}\left(A=0.000143326950088, B=1300.0\right)$$
R469ICHOO + HO2→0.35 ICPDH + 0.52 CO + 0.13 MVKHC + 0.65 HO2 + 0.65 OH + 0.65 CH2O + 0.52 HAC$$\mathrm{arrhenius_M}\left(A=0.000143326950088, B=1300.0\right)$$
R470NO + ICHOO→ITCN$$\frac{\frac{0.0005837829674919263 \cdot e^{\frac{350.0}{T}} \cdot num_{density}^{2} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}}}{\left(13.098 + \frac{0.3590349719522309 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}}}{1.0 + \frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{0.3590349719522309 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R471NO + ICHOO→0.8 CO + 0.2 MVKHC + NO2 + HO2 + 0.8 HAC + CH2O$$\mathrm{troe_clamp_arr_M}\left(A=0.0212970599121096, B=13.098, Fc=0.3590349719522309, M0=0.8349650510516997\right)$$
R472ICHOO→2 CO + HO2 + OH + HAC$$\mathrm{arrhenius}\left(A=18750000000000.0, B=-10000.0\right)$$
R473NO + HPALD1OO→MVK + NO2 + CO2 + OH$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=350.0\right)$$
R474HPALD1OO + HO2→MVK + CO2 + 2 OH$$\mathrm{arrhenius_M}\left(A=0.000143326950088, B=1300.0\right)$$
R475NO + HPALD2OO→NO2 + CO2 + OH + MACR$$\mathrm{arrhenius_M}\left(A=0.0016259780052, B=350.0\right)$$
R476HPALD2OO + HO2→CO2 + 2 OH + MACR$$\mathrm{arrhenius_M}\left(A=0.000143326950088, B=1300.0\right)$$
R477IHN2 + OH→ISOPNOO1$$\mathrm{arrhenius_M}\left(A=0.0042998085026399995, B=390.0\right)$$
R478IHN2 + OH→0.33 IEPOXB + NO2 + 0.67 IEPOXA$$\mathrm{arrhenius_M_div_lin}\left(A=0.0037939486788000007, B=390.0, C=0.097558680312\right)$$
R479IHN3 + OH→ISOPNOO2$$\mathrm{arrhenius_M}\left(A=0.0061425835752, B=390.0\right)$$
R480IHN3 + OH→0.33 IEPOXB + NO2 + 0.67 IEPOXA$$\mathrm{arrhenius_M_div_lin}\left(A=0.006323247798, B=390.0, C=0.149951304924\right)$$
R481OH + IHN1→IEPOXD + NO2$$\mathrm{arrhenius_M_div_lin}\left(A=0.009334318178000001, B=390.0, C=0.16350112163400002\right)$$
R482OH + IHN1→IDHNDOO1$$\mathrm{arrhenius_M}\left(A=0.012285167150400001, B=390.0\right)$$
R483IHN4 + OH→IEPOXD + NO2$$\mathrm{arrhenius_M_div_lin}\left(A=0.00573307800352, B=390.0, C=0.16350112163400002\right)$$
R484IHN4 + OH→IDHNDOO2$$\mathrm{arrhenius_M}\left(A=0.017765315242000004, B=390.0\right)$$
R485OH + IHN1→0.6 CO + 0.6 MCRHNB + 0.4 ICN + 0.4 HO2 + 0.6 OH$$\mathrm{arrhenius_M}\left(A=0.00451660557, B=20.0\right)$$
R486IHN4 + OH→0.6 CO + 0.4 ICN + 0.4 HO2 + 0.6 OH + 0.6 MVKN$$\mathrm{arrhenius_M}\left(A=0.00451660557, B=20.0\right)$$
R487ISOPNOO1→HO2 + ITCN$$\mathrm{arrhenius}\left(A=18750000000000.0, B=-10000.0\right)$$
R488ISOPNOO1 + HO2→0.482 ITHN + 0.059 MCRHN + 0.459 GLYC + 0.459 NO2 + 0.059 HO2 + 0.518 OH + 0.059 CH2O + 0.459 HAC$$\mathrm{arrhenius_M}\left(A=0.00015657565976000002, B=1300.0\right)$$
R489NO + ISOPNOO1→0.272 MCRHN + 0.728 GLYC + 1.728 NO2 + 0.272 HO2 + 0.272 CH2O + 0.728 HAC$$\mathrm{troe_clamp_arr_M}\left(A=0.010276180992864, B=6.32, Fc=7.211410185862182, M0=16.77072136247019\right)$$
R490NO + ISOPNOO1→IDN$$\frac{\frac{0.011725594348687151 \cdot e^{\frac{350.0}{T}} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}^{2}}{\left(6.32 + \frac{7.211410185862182 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R491ISOPNOO2→HO2 + ITCN$$\mathrm{arrhenius}\left(A=18750000000000.0, B=-10000.0\right)$$
R492HO2 + ISOPNOO2→0.401 ITHN + 0.599 HO2 + 0.599 MVKN + 0.599 CH2O + 0.599 OH$$\mathrm{arrhenius_M}\left(A=0.00015657565976, B=1300.0\right)$$
R493NO + ISOPNOO2→NO2 + HO2 + MVKN + CH2O$$\mathrm{troe_clamp_arr_M}\left(A=0.012911891339293198, B=7.941, Fc=7.211410185862182, M0=16.77072136247019\right)$$
R494NO + ISOPNOO2→IDN$$\frac{\frac{0.011725594348687151 \cdot e^{\frac{350.0}{T}} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}^{2}}{\left(1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right) \cdot \left(7.941 + \frac{7.211410185862182 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right)} + \left
R495IDHNDOO1→HO2 + ITCN$$\mathrm{arrhenius}\left(A=12560000000000.0, B=-10000.0\right)$$
R496IDHNDOO2→HO2 + ITCN$$\mathrm{arrhenius}\left(A=5092000000000.0, B=-10000.0\right)$$
R497HO2 + IDHNDOO1→0.418 ITHN + 0.551 PROPNN + 0.031 MCRHNB + 0.551 GLYC + 0.582 HO2 + 0.582 OH + 0.031 CH2O$$\mathrm{arrhenius_M}\left(A=0.00015657565976, B=1300.0\right)$$
R498NO + IDHNDOO1→0.935 PROPNN + 0.065 MCRHNB + 0.935 GLYC + NO2 + HO2 + 0.065 CH2O$$\mathrm{troe_clamp_arr_M}\left(A=0.007661608360502399, B=4.712, Fc=7.211410185862182, M0=16.77072136247019\right)$$
R499NO + IDHNDOO1→IDN$$\frac{\frac{0.011725594348687151 \cdot e^{\frac{350.0}{T}} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}^{2}}{\left(4.712 + \frac{7.211410185862182 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R500HO2 + IDHNDOO2→0.065 CH2O + 0.506 OH + 0.494 ITHN + 0.506 HO2 + 0.065 MVKN + 0.441 HAC + 0.441 ETHLN$$\mathrm{arrhenius_M}\left(A=0.00015657565976000002, B=1300.0\right)$$
R501NO + IDHNDOO2→0.142 CH2O + NO2 + HO2 + 0.142 MVKN + 0.858 HAC + 0.858 ETHLN$$\mathrm{troe_clamp_arr_M}\left(A=0.0036714583357415997, B=2.258, Fc=7.211410185862182, M0=16.77072136247019\right)$$
R502NO + IDHNDOO2→IDN$$\frac{\frac{0.011725594348687151 \cdot e^{\frac{350.0}{T}} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}^{2}}{\left(2.258 + \frac{7.211410185862182 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right) \cdot \left(1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)} + \left
R503HO2 + IDHNBOO→0.033 ETHLN + 0.104 CH2O + 0.621 ITHN + 0.094 MCRHNB + 0.242 PROPNN + 0.242 GLYC + 0.379 HO2 + 0.379 OH + 0.01 MVKN + 0.033 HAC$$\mathrm{arrhenius_M}\left(A=0.00015657565976, B=1300.0\right)$$
R504NO + IDHNBOO→0.383 CH2O + 0.546 PROPNN + 0.355 MCRHNB + 0.546 GLYC + NO2 + HO2 + 0.028 MVKN + 0.071 HAC + 0.071 ETHLN$$\mathrm{troe_clamp_arr_M}\left(A=0.0030096852876251995, B=1.851, Fc=7.211410185862182, M0=16.77072136247019\right)$$
R505NO + IDHNBOO→IDN$$\frac{\frac{0.011725594348687151 \cdot e^{\frac{350.0}{T}} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}^{2}}{\left(1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right) \cdot \left(1.851 + \frac{7.211410185862182 \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(\frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}\right)^{2}}} \cdot num_{density}}{1.0 + \frac{7.211410185862182 \cdot num_{density}}{0.43 \cdot \frac{298.0}{T}^{8}}}\right)} + \left
R506ISOP + NO3→0.465 INO2B + LISOPNO3 + 0.535 INO2D$$\mathrm{arrhenius_M}\left(A=0.0017765315242000003, B=450.0\right)$$
R507INO2B + HO2→0.479 MVK + 0.473 INPB + 0.527 NO2 + 0.048 MACR + 0.527 OH + 0.527 CH2O$$\mathrm{arrhenius_M}\left(A=0.000148746876772, B=1300.0\right)$$
R508HO2 + INO2D→INPD$$\mathrm{arrhenius_M}\left(A=0.00014874687677200003, B=1300.0\right)$$
R5092 INO2B→1.737 MVK + 0.07 INPB + 1.86 NO2 + 0.07 ICN + 0.123 MACR + 1.86 CH2O$$\mathrm{scaled_M}\left(A=0.00096956466236\right)$$
R510INO2B + INO2D→0.544 MVK + 0.399 INPB + 0.474 INA + 0.532 ICN + 0.563 NO2 + 0.089 HO2 + 0.019 MACR + 0.563 CH2O + 0.032 IHN1$$\mathrm{scaled_M}\left(A=0.0015416680345600002\right)$$
R5112 INO2D→0.127 IHN4 + 0.34 INA + 0.861 ICN + 0.064 HO2 + 0.671 IHN1$$\mathrm{scaled_M}\left(A=0.0022342142219600003\right)$$
R512MO2 + INO2D→0.645 CH2O + 0.057 IHN4 + 0.244 INA + 0.401 ICN + 0.336 HO2 + 0.355 MOH + 0.298 IHN1$$\mathrm{scaled_M}\left(A=0.0007106126096800001\right)$$
R513MO2 + INO2B→0.583 MVK + 0.355 INPB + 0.034 ICN + 0.611 NO2 + 0.611 HO2 + 0.028 MACR + 1.577 CH2O + 0.034 MOH$$\mathrm{scaled_M}\left(A=0.00016861994128000002\right)$$
R514MCO3 + INO2B→0.903 MVK + MO2 + NO2 + 0.097 MACR + CH2O$$\mathrm{scaled_M}\left(A=0.00115625102592\right)$$
R515MCO3 + INO2D→MO2 + 0.841 INA + 0.159 ICN + 0.159 HO2$$\mathrm{scaled_M}\left(A=0.00464307052596\right)$$
R516NO3 + INO2B→0.903 MVK + 2 NO2 + 0.097 MACR + CH2O$$\mathrm{scaled_M}\left(A=0.0013850923748000002\right)$$
R517NO3 + INO2D→0.841 INA + NO2 + 0.159 ICN + 0.159 HO2$$\mathrm{scaled_M}\left(A=0.0013850923748000002\right)$$
R518NO + INO2B→0.904 MVK + 2 NO2 + 0.096 MACR + CH2O$$\mathrm{troe_clamp_arr_M}\left(A=0.020999505937158, B=12.915, Fc=0.9759582400390522, M0=2.2696703256722146\right)$$
R519NO + INO2B→IDN$$\mathrm{troe_clamp_jpl_alt}\left(A=0.0015868866322972007, Fc=0.9759582400390522, B=12.915\right)$$
R520NO + INO2D→0.841 INA + NO2 + 0.159 ICN + 0.159 HO2$$\mathrm{troe_clamp_arr_M}\left(A=0.0022958809433424, B=1.412, Fc=0.9759582400390522, M0=2.2696703256722146\right)$$
R521NO + INO2D→IDN$$\mathrm{troe_clamp_jpl_alt}\left(A=0.0015868866322972007, Fc=0.9759582400390522, B=1.412\right)$$
R522INA + O2→ICN + HO2$$\mathrm{arrhenius_M}\left(A=1.50553519 \times 10^{-5}, B=-300.0\right)$$
R523INA→IDHNBOO$$\mathrm{arrhenius}\left(A=1 \times 10^{20}, B=-10000.0\right)$$
R524INPB + OH→0.67 IHPNBOO + 0.33 IDHNBOO$$\mathrm{arrhenius_M}\left(A=0.0035410187668800004, B=390.0\right)$$
R525INPD + OH→IHPNDOO$$\mathrm{arrhenius_M}\left(A=0.0096956466236, B=390.0\right)$$
R526INPB + OH→ITHN + OH$$\mathrm{arrhenius_M_div_lin}\left(A=0.002692499133796, B=390.0, C=0.013730480932799998\right)$$
R527INPD + OH→ITHN + OH$$\mathrm{arrhenius_M_div_lin}\left(A=0.005281417446520001, B=390.0, C=0.0131583775606\right)$$
R528INPD + OH→ICHE + NO2$$\mathrm{arrhenius_M_div_lin}\left(A=0.00899105615468, B=390.0, C=0.16350112163400002\right)$$
R529INPB + OH→INO2B$$\mathrm{arrhenius_M}\left(A=0.0013718436651280004, B=200.0\right)$$
R530INPD + OH→INO2D$$\mathrm{arrhenius_M}\left(A=0.0020475278584000003, B=200.0\right)$$
R531INPD + OH→ICN + OH$$\mathrm{arrhenius_M}\left(A=0.00451660557, B=20.0\right)$$
R532IHPNDOO→OH + ITCN$$\mathrm{arrhenius}\left(A=6550000000000.0, B=-10000.0\right)$$
R533IHPNBOO→0.5 ITHN + OH + 0.5 ITCN$$\mathrm{arrhenius}\left(A=8720000000000.0, B=-10000.0\right)$$
R534IHPNBOO + HO2→0.051 ETHLN + 0.06 MCRHNB + 0.249 HPETHNL + 0.008 MVKN + 0.004 MCRHP + 0.34 GLYC + 0.009 ATOOH + 0.058 NO2 + 0.326 HO2 + 1.147 OH + 0.054 MVKHP + 0.234 ITHN + 0.589 PROPNN + 0.042 HAC + 0.126 CH2O$$\mathrm{arrhenius_M}\left(A=0.000158984516064, B=1300.0\right)$$
R535IHPNDOO + HO2→0.054 ETHLN + 0.387 ITHN + 0.073 MCRHNB + 0.054 ATOOH + 0.471 HPETHNL + 0.471 PROPNN + 0.58 HO2 + 0.015 MVKN + 0.646 OH + 0.088 CH2O$$\mathrm{arrhenius_M}\left(A=0.000158984516064, B=1300.0\right)$$
R536NO + IHPNBOO→0.051 HAC + 0.17 MCRHNB + 0.303 HPETHNL + 0.014 MVKN + 0.006 MCRHP + 0.384 GLYC + 0.013 ATOOH + 1.065 NO2 + 0.5 HO2 + 0.435 OH + 0.059 MVKHP + 0.687 PROPNN + 0.249 CH2O + 0.064 ETHLN$$\mathrm{troe_clamp_arr_M}\left(A=0.009905458007678399, B=6.092, Fc=19.602645265793633, M0=45.587547129752636\right)$$
R537NO + IHPNBOO→IDN$$\mathrm{troe_clamp_jpl_alt}\left(A=0.03187347004591835, Fc=19.602645265793633, B=6.092\right)$$
R538NO + IHPNDOO→0.096 OH + 0.59 PROPNN + 0.291 MCRHNB + 0.07 ATOOH + 0.59 HPETHNL + NO2 + 0.904 HO2 + 0.049 MVKN + 0.34 CH2O + 0.07 ETHLN$$\mathrm{troe_clamp_arr_M}\left(A=0.0071266615967916, B=4.383, Fc=19.602645265793633, M0=45.587547129752636\right)$$
R539NO + IHPNDOO→IDN$$\mathrm{troe_clamp_jpl_alt}\left(A=0.03187347004591835, Fc=19.602645265793633, B=4.383\right)$$
R540ICN + OH→ICHE + NO2$$\mathrm{arrhenius_M_div_lin}\left(A=0.0017885758057200002, B=390.0, C=0.16350112163400002\right)$$
R541ICN + OH→0.539 CO + 0.378 MCRHNB + 0.461 ICNOO + 0.295 HO2 + 0.244 OH + 0.161 MVKN$$\mathrm{arrhenius_M}\left(A=0.0056307016106, B=390.0\right)$$
R542NO + ICNOO→0.33 CO + 0.231 PROPNN + 0.67 ICNOO + NO2 + 0.33 HO2 + 0.33 CO2 + 0.099 ETHLN$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=350.0\right)$$
R543ICNOO + HO2→0.33 CO + 0.231 PROPNN + 0.67 ICNOO + 0.33 HO2 + 0.33 CO2 + OH + 0.099 ETHLN$$\mathrm{arrhenius_M}\left(A=0.00015296237530399999, B=1300.0\right)$$
R544IDN + OH→0.565 ITHN + 0.435 IDNOO + 0.565 NO2$$0.00602214076 \cdot e^{0.0} \cdot num_{density}$$
R545NO + IDNOO→PROPNN + 0.11 GLYC + 1.11 NO2 + 0.89 HO2 + 0.89 ETHLN$$\mathrm{arrhenius_M}\left(A=0.0016259780052, B=350.0\right)$$
R546IDNOO + HO2→0.82 PROPNN + 0.09 GLYC + 0.09 NO2 + 0.18 IDN + 0.73 HO2 + 0.82 OH + 0.73 ETHLN$$\mathrm{arrhenius_M}\left(A=0.000163200014596, B=1300.0\right)$$
R547MVK + OH→MVKOHOO$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=610.0\right)$$
R548MVK + O3→0.18 CO + 0.38 MCO3 + 0.075 PYAC + 0.5 CH2OO + 0.545 MGLY + 0.1 HO2 + 0.045 H2O2 + 0.08 OH + 0.6 CH2O$$\mathrm{arrhenius_M}\left(A=5.118819646 \times 10^{-7}, B=-1520.0\right)$$
R549MACR + OH→0.036 CO + 0.036 ATOOH + 0.964 MCROHOO + 0.036 HO2$$\mathrm{arrhenius_M}\left(A=0.0026497419344, B=380.0\right)$$
R550MACR + OH→MACR1OO$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=470.0\right)$$
R551O3 + MACR→0.12 CO + 0.12 MCO3 + 0.88 CH2OO + 0.88 MGLY + 0.12 OH + 0.12 CH2O$$\mathrm{arrhenius_M}\left(A=8.430997064 \times 10^{-7}, B=-2100.0\right)$$
R552NO3 + MACR→0.68 CO + 0.68 PROPNN + 0.32 HNO3 + 0.32 MACR1OO + 0.68 OH$$\mathrm{arrhenius_M}\left(A=0.00010839853368, B=-1190.0\right)$$
R553MVKN + OH→0.241 PYAC + 0.04 MCO3 + 0.69 NO3 + 0.29 MVKHCB + 0.449 MGLY + 0.31 NO2 + 0.449 HCOOH + 0.02 OH + 0.241 CH2O$$\mathrm{arrhenius_M}\left(A=0.00074674545424, B=380.0\right)$$
R554MVKHP + OH→0.53 MVKHC + 0.47 MVKHCB + OH$$\mathrm{scaled_M}\left(A=0.0347477521852\right)$$
R555OH + MCRHP→0.77 CO + 0.23 ATOOH + 0.23 CO2 + OH + 0.77 HAC$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=470.0\right)$$
R556MCRHN + OH→MACRNO2$$\mathrm{arrhenius_M}\left(A=0.0083707756564, B=380.0\right)$$
R557MCRHNB + OH→0.25 CO + PROPNN + 0.75 CO2 + OH$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=470.0\right)$$
R558C4HVP1 + NO→MVKOHOO + NO2$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=350.0\right)$$
R559C4HVP1 + HO2→MVKOHOO + OH$$\mathrm{arrhenius_M}\left(A=0.000116227316668, B=1300.0\right)$$
R560C4HVP1 + NO2→MVKN$$\mathrm{scaled_M}\left(A=0.005419926684000001\right)$$
R561NO + C4HVP2→MCROHOO + NO2$$\mathrm{arrhenius_M}\left(A=0.0016259780052, B=350.0\right)$$
R562HO2 + C4HVP2→MCROHOO + OH$$\mathrm{arrhenius_M}\left(A=0.000116227316668, B=1300.0\right)$$
R563NO2 + C4HVP2→MCRHN$$\mathrm{scaled_M}\left(A=0.005419926684000001\right)$$
R564MCRENOL + OH→0.75 CO + 0.653 PYAC + 0.097 MCO3 + 0.063 MVKHCB + 0.187 MGLY + 0.715 HO2 + 0.097 CO2 + 0.285 OH + 0.187 HCOOH$$\mathrm{arrhenius_M}\left(A=0.00223421422196, B=983.0\right)$$
R565MVKPC + OH→CO + MGLY + OH$$\mathrm{arrhenius_M}\left(A=0.00301107038, B=470.0\right)$$
R566MVKDH + OH→0.6 MVKHC + 0.4 MVKHCB + HO2$$\mathrm{arrhenius_M}\left(A=0.0052392624612, B=70.0\right)$$
R567MVKHCB + OH→MGLY + OH$$\mathrm{arrhenius_M}\left(A=0.00301107038, B=470.0\right)$$
R568MVKHC + OH→2 CO + MCO3 + HO2$$\mathrm{arrhenius_M}\left(A=0.001204428152, B=70.0\right)$$
R569MCRDH + OH→0.84 CO + 0.16 MVKHCB + HO2 + 0.84 HAC$$\mathrm{arrhenius_M}\left(A=0.014453137824000001, B=70.0\right)$$
R570MVKOHOO + HO2→0.36 MCO3 + 0.335 MVKHP + 0.255 MVKHC + 0.36 GLYC + 0.05 MGLY + 0.305 HO2 + 0.665 OH + 0.05 CH2O$$\mathrm{arrhenius_M}\left(A=0.000127669384112, B=1300.0\right)$$
R571MVKOHOO + NO→0.758 MCO3 + 0.758 GLYC + NO2 + 0.242 MGLY + 0.242 HO2 + 0.242 CH2O$$\frac{\frac{0.0074355974177796 \cdot e^{\frac{350.0}{T}} \cdot num_{density}}{4.573 + \frac{0.04859009962100446 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}}}{1.0 + 0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left
R572MVKOHOO + NO→0.438 MVKN$$\mathrm{troe_clamp_jpl_alt}\left(A=7.90064332542301 \times 10^{-5}, Fc=0.04859009962100446, B=4.573\right)$$
R573MCROHOO + HO2→0.59 O2 + 0.507 CO + 0.083 CH2O + 0.083 MGLY + 0.507 HO2 + 0.59 OH + 0.41 MCRHP + 0.507 HAC$$\mathrm{arrhenius_M}\left(A=0.000127669384112, B=1300.0\right)$$
R574MACR1OO + HO2→0.325 CO + 0.5 MACR1OOH + 0.325 MO2 + 0.175 MCO3 + 0.13 O3 + 0.5 CO2 + 0.5 OH + 0.5 CH2O$$\mathrm{arrhenius_M}\left(A=0.00189095219864, B=580.0\right)$$
R575MACR1OOH + OH→0.488 CO + 0.087 MCO3 + 0.162 MO2 + 0.165 MACR1OO + 0.098 HMML + 0.415 CO2 + 0.585 OH + 0.488 HAC + 0.25 CH2O$$\mathrm{scaled_M}\left(A=0.0099967536616\right)$$
R576MCROHOO→CO + OH + HAC$$\mathrm{arrhenius}\left(A=29000000.0, B=-5297.0\right)$$
R577NO + MCROHOO→0.86 CO + NO2 + 0.14 MGLY + 0.86 HO2 + 0.86 HAC + 0.14 CH2O$$\frac{\frac{0.004853544345522 \cdot e^{\frac{350.0}{T}} \cdot num_{density}}{2.985 + \frac{0.04859009962100446 \cdot num_{density} \cdot 0.41^{\frac{1.0}{1.0 + \log_{10}\left(0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}\right)^{2}}}}{1.0 + 0.11300023167675458 \cdot num_{density} \cdot \frac{298.0}{T}^{8}}} + \left
R578NO + MCROHOO→MCRHN$$\mathrm{troe_clamp_jpl_alt}\left(A=7.90064332542301 \times 10^{-5}, Fc=0.04859009962100446, B=2.985\right)$$
R579NO + MACR1OO→0.65 CO + 0.35 MCO3 + 0.65 MO2 + NO2 + CO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0052392624612, B=290.0\right)$$
R580MACR1OO + NO2→MPAN$$\frac{1.0571137948401692 \times 10^{-12} \cdot 10.0^{\frac{-0.5228787452803376}{1.0 + \frac{\log_{10}\left(\frac{1.560336670916 \times 10^{-10} \cdot num_{density}}{1.125 \times 10^{-11} \cdot \frac{T}{300}^{5.765000000000001}}\right)}{1.4140560065060288}^{2}}} \cdot num_{density}^{2}}{\frac{T}{300}^{7.975} \cdot \left(\frac{1.125 \times 10^{-11}}{\frac{T}{300}^{1.105}} + \frac{1.560336670916 \times 10^{-10} \cdot num_{density}}{\frac{T}{300}^{6.87}}\right)}$$
R581MACRNO2 + HO2→0.13 O3 + 0.13 MCRHNB + 0.37 MCRHN + 0.5 NO2 + 0.5 CO2 + 0.5 OH + 0.5 HAC$$\mathrm{arrhenius_M}\left(A=0.0018909521986400003, B=580.0\right)$$
R582NO + MACRNO2→2 NO2 + CO2 + HAC$$\mathrm{arrhenius_M}\left(A=0.00451660557, B=290.0\right)$$
R583MACRNO2 + NO2→MPAN + NO2$$\frac{1.0571137948401692 \times 10^{-12} \cdot 10.0^{\frac{-0.5228787452803376}{1.0 + \frac{\log_{10}\left(\frac{1.560336670916 \times 10^{-10} \cdot num_{density}}{1.125 \times 10^{-11} \cdot \frac{T}{300}^{5.765000000000001}}\right)}{1.4140560065060288}^{2}}} \cdot num_{density}^{2}}{\frac{T}{300}^{7.975} \cdot \left(\frac{1.125 \times 10^{-11}}{\frac{T}{300}^{1.105}} + \frac{1.560336670916 \times 10^{-10} \cdot num_{density}}{\frac{T}{300}^{6.87}}\right)}$$
R584MACRNO2 + NO3→2 NO2 + CO2 + HAC$$\mathrm{scaled_M}\left(A=0.002408856304\right)$$
R585MO2 + MACRNO2→0.3 MCRHNB + 0.7 NO2 + 0.7 HO2 + 0.7 CO2 + 0.7 HAC + CH2O$$\mathrm{arrhenius_M}\left(A=0.0017464208204000002, B=500.0\right)$$
R586MPAN→MACR1OO + NO2$$\mathrm{arrhenius}\left(A=1.58 \times 10^{16}, B=-13500.0\right)$$
R587MPAN + OH→0.25 CO + NO3 + 0.75 HMML + 0.25 HAC$$\mathrm{scaled_M}\left(A=0.017464208204\right)$$
R588HMML + OH→0.3 MCO3 + 0.7 MGLY + 0.3 HCOOH + 0.7 OH$$\mathrm{scaled_M}\left(A=0.00260758694908\right)$$
R589ICPDH + OH→0.15 MCRDH + CO + 0.35 MVKDH + 0.5 HO2 + 0.5 OH + 0.5 MCRHP$$\mathrm{scaled_M}\left(A=0.006022140759999999\right)$$
R590IDCHP + OH→0.444 MVKPC + 0.888 CO + 0.032 IEPOXBOO + 0.318 MVKHC + 0.126 MVKHCB + 0.444 HO2 + 0.444 OH + 0.08 IEPOXAOO$$\mathrm{scaled_M}\left(A=0.013549816710000002\right)$$
R591IDHDP + OH→0.333 ICPDH + 0.667 IDHPE + OH$$\mathrm{scaled_M}\left(A=0.001806642228\right)$$
R592IDHPE + OH→0.429 MVKHP + CO2 + OH + 0.571 MCRHP$$\mathrm{scaled_M}\left(A=0.001806642228\right)$$
R593OH + ITCN→CO + 0.75 MVKHP + NO2 + 0.25 MCRHP$$\mathrm{scaled_M}\left(A=0.006022140759999999\right)$$
R594ITHN + OH→0.022 MCRENOL + 0.022 CH2O + 0.041 ICNOO + 0.022 NO2 + 0.62 HO2 + 0.3 OH + 0.92 ITCN + 0.037 IDHNBOO$$\mathrm{scaled_M}\left(A=0.001806642228\right)$$
R595NO3 + ETHLN→MCO3 + HNO3 + NO2$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=-1860.0\right)$$
R596PYAC + OH→MCO3 + CO2$$\mathrm{scaled_M}\left(A=0.0004817712608\right)$$
R597HMHP + OH→0.5 HO2 + 0.5 HCOOH + 0.5 OH + 0.5 CH2O$$\mathrm{arrhenius_M}\left(A=0.0007828782988, B=500.0\right)$$
R598MCO3 + HO2→0.13 O3 + 0.5 MO2 + 0.37 MAP + 0.13 ACTA + 0.5 CO2 + 0.5 OH$$\mathrm{arrhenius_M}\left(A=0.0018909521986400003, B=580.0\right)$$
R599HPETHNL + OH→CO + OH + CH2O$$\mathrm{arrhenius_M}\left(A=0.0009334318178, B=340.0\right)$$
R600HPETHNL + OH→GLYX + OH$$\mathrm{scaled_M}\left(A=0.017524429611599997\right)$$
R601NAP + OH→NRO2 + OH$$\mathrm{arrhenius_M}\left(A=0.0093945395856, B=117.0\right)$$
R602NRO2 + HO2→LNRO2H + HO2$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=700.0\right)$$
R603NO + NRO2→NO + LNRO2N$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=350.0\right)$$
R604O3 + C2H4→CH2OO + CH2O$$\mathrm{arrhenius_M}\left(A=5.4801480916 \times 10^{-6}, B=-2580.0\right)$$
R605C2H4 + OH→ETOO$$\frac{0.039892797266578704 \cdot e^{0.0} \cdot 0.5^{\frac{1.0}{1.0 + \log_{10}\left(7.886136709523809 \cdot \frac{300}{T}^{1.75} \cdot num_{density}\right)^{2}}} \cdot num_{density}^{2} \cdot \frac{300}{T}^{3.5}}{1.0 + 7.886136709523809 \cdot \frac{300}{T}^{1.75} \cdot num_{density}}$$
R606C2H2 + OH→0.636 GLYX + 0.364 CO + 0.364 HO2 + 0.364 HCOOH + 0.636 OH$$\frac{0.0019946398633289356 \cdot e^{0.0} \cdot 0.5^{\frac{1.0}{1.0 + \log_{10}\left(3.9905752024096386 \cdot \frac{300}{T}^{2.0} \cdot num_{density}\right)^{2}}} \cdot num_{density}^{2}}{1.0 + 3.9905752024096386 \cdot \frac{300}{T}^{2.0} \cdot num_{density}}$$
R607ETOO + HO2→ETHP$$\mathrm{arrhenius_M}\left(A=9.2138753628 \times 10^{-5}, B=1300.0\right)$$
R608NO + ETOO→0.005 ETHN + 0.995 ETO + 0.995 NO2$$\mathrm{arrhenius_M}\left(A=0.0016259780051999999, B=360.0\right)$$
R609NO3 + ETOO→ETO + NO2$$\mathrm{scaled_M}\left(A=0.0013850923748000002\right)$$
R610MO2 + ETOO→0.2 ETHP + 0.6 ETO + 0.2 GLYC + 0.6 HO2 + 0.8 CH2O + 0.2 MOH$$\mathrm{scaled_M}\left(A=0.0003613284456\right)$$
R611ETO→HO2 + 2 CH2O$$\mathrm{arrhenius}\left(A=95000000000000.0, B=-5988.0\right)$$
R612ETO + O2→GLYC + HO2$$\mathrm{arrhenius_M}\left(A=1.50553519 \times 10^{-5}, B=-300.0\right)$$
R613ETHN + OH→GLYC + NO2$$\mathrm{scaled_M}\left(A=0.0005058598238399999\right)$$
R614ETHP + OH→ETOO$$\mathrm{arrhenius_M}\left(A=0.0011442067444000002, B=190.0\right)$$
R615ETHP + OH→GLYC + OH$$\mathrm{scaled_M}\left(A=0.008310554248800001\right)$$
R616BENZ + OH→0.18 GLYX + 0.2 CO + 0.46 AROMRO2 + BRO2 + 0.54 PHEN + 0.54 HO2 + 0.56 AROMP4$$\mathrm{arrhenius_M}\left(A=0.0013850923748, B=-193.0\right)$$
R617TOLU + OH→0.12 GLYX + TRO2 + 0.06 BALD + 0.04 MVK + 0.19 CSL + 0.3 AROMP5 + 0.27 CO + 0.19 HO2 + 0.81 AROMRO2 + 0.12 MGLY + 0.68 AROMP4$$\mathrm{arrhenius_M}\left(A=0.0010839853368, B=340.0\right)$$
R618OH + XYLE→0.1 GLYX + 0.06 BALD + 0.04 MVK + XRO2 + 0.15 CSL + 0.56 AROMP5 + 0.3 CO + 0.15 HO2 + 0.45 RCOOH + 0.85 AROMRO2 + 0.2 MGLY + 0.28 AROMP4$$\mathrm{scaled_M}\left(A=0.010237639292\right)$$
R619AROMRO2 + HO2→HO2 + OH$$\mathrm{arrhenius_M}\left(A=0.00014370032281512, B=1300.0\right)$$
R620NO + AROMRO2→NO2 + HO2$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=365.0\right)$$
R621NO3 + AROMRO2→NO2 + HO2$$\mathrm{scaled_M}\left(A=0.0013850923748000002\right)$$
R622MO2 + AROMRO2→2 HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=1.0237639292 \times 10^{-5}, B=220.0\right)$$
R623MCO3 + AROMRO2→MO2 + HO2$$\mathrm{arrhenius_M}\left(A=2.5292991192 \times 10^{-5}, B=220.0\right)$$
R624PHEN + OH→0.06 GLYX + 0.8 MCT + 0.06 BENZO + 0.14 AROMRO2 + 0.8 HO2 + 0.18 AROMP4$$\mathrm{arrhenius_M}\left(A=0.00028304061572, B=1220.0\right)$$
R625NO3 + PHEN→0.742 HNO3 + 0.742 BENZO + 0.258 NPHEN$$\mathrm{scaled_M}\left(A=0.0022884134888\right)$$
R626CSL + OH→0.727 MCT + 0.2 AROMRO2 + 0.073 BENZO + 0.727 HO2 + 0.44 AROMP5$$\mathrm{scaled_M}\left(A=0.028304061572\right)$$
R627CSL + NO3→0.5 HNO3 + 0.2 AROMRO2 + 0.3 BENZO + 0.5 NPHEN + 0.44 AROMP5$$\mathrm{scaled_M}\left(A=0.008430997064\right)$$
R628MCT + OH→0.3 BENZO + 0.7 AROMRO2 + 1.05 AROMP4$$\mathrm{scaled_M}\left(A=0.012044281519999998\right)$$
R629O3 + MCT→GLYC + HO2 + OH + AROMP4$$\mathrm{scaled_M}\left(A=5.540369499200001 \times 10^{-9}\right)$$
R630MCT + NO3→0.5 HNO3 + 0.3 BENZO + 0.2 AROMRO2 + 0.5 NPHEN + 0.3 AROMP4$$\mathrm{scaled_M}\left(A=0.05961919352399999\right)$$
R631BALD + OH→BZCO3$$\mathrm{arrhenius_M}\left(A=0.0035530630484, B=225.0\right)$$
R632BALD + NO3→HNO3 + BZCO3$$\mathrm{scaled_M}\left(A=1.4453137823999998 \times 10^{-6}\right)$$
R633HO2 + BZCO3→0.2 BENZO2 + 0.15 O3 + 0.15 BENZP + 0.65 BZCO3H + 0.35 CO2 + 0.2 OH$$\mathrm{arrhenius_M}\left(A=0.006624354836000001, B=340.0\right)$$
R634NO + BZCO3→BENZO2 + NO2 + CO2$$\mathrm{arrhenius_M}\left(A=0.00451660557, B=290.0\right)$$
R635NO2 + BZCO3→BZPAN$$\frac{1.3382220173970497 \times 10^{-12} \cdot 10.0^{\frac{-0.5228787452803376}{1.0 + \frac{\log_{10}\left(\frac{1.97526216928 \times 10^{-10} \cdot num_{density}}{1.125 \times 10^{-11} \cdot \frac{T}{300}^{5.765000000000001}}\right)}{1.4140560065060288}^{2}}} \cdot num_{density}^{2}}{\frac{T}{300}^{7.975} \cdot \left(\frac{1.125 \times 10^{-11}}{\frac{T}{300}^{1.105}} + \frac{1.97526216928 \times 10^{-10} \cdot num_{density}}{\frac{T}{300}^{6.87}}\right)}$$
R636BZCO3H + OH→BZCO3$$\mathrm{scaled_M}\left(A=0.00280631759416\right)$$
R637BZPAN→NO2 + BZCO3$$\frac{8.432803706228 \times 10^{29} \cdot e^{\frac{-14100.0}{T}} \cdot e^{\frac{-10100.0}{T}} \cdot 10.0^{\frac{-0.5228787452803376}{1.0 + \frac{\log_{10}\left(\frac{6624354836000.0 \cdot e^{\frac{-10100.0}{T}} \cdot num_{density}}{1.9 \times 10^{17} \cdot e^{\frac{-14100.0}{T}}}\right)}{1.4140560065060288}^{2}}} \cdot num_{density}}{1.9 \times 10^{17} \cdot e^{\frac{-14100.0}{T}} + 6624354836000.0 \cdot e^{\frac{-10100.0}{T}} \cdot num_{density}}$$
R638OH + BZPAN→BENZP + NO2 + CO2$$\mathrm{scaled_M}\left(A=0.00063834692056\right)$$
R639BENZO2 + NO2→NO3 + BENZO$$\mathrm{scaled_M}\left(A=0.004215498532\right)$$
R640BENZO2 + NO→BENZO + NO2$$\mathrm{arrhenius_M}\left(A=0.00160791158292, B=365.0\right)$$
R641BENZO2 + NO3→BENZO + NO2$$\mathrm{scaled_M}\left(A=0.0013850923748000002\right)$$
R642BENZO2 + HO2→BENZP$$\mathrm{arrhenius_M}\left(A=0.00013489595302400002, B=1300.0\right)$$
R643BENZP + OH→BENZO2$$\mathrm{scaled_M}\left(A=0.0021679706736\right)$$
R644O3 + BENZO→BENZO2$$\mathrm{scaled_M}\left(A=0.000172233225736\right)$$
R645BENZO + NO2→NPHEN$$\mathrm{scaled_M}\left(A=0.0012526052780800002\right)$$
R646NPHEN + OH→0.5 R4N1 + 0.5 NO2 + AROMP4$$\mathrm{scaled_M}\left(A=0.00208968284372\right)$$
R647NO3 + NPHEN→0.5 R4N1 + 0.5 HNO3 + NO2 + AROMP4$$\mathrm{scaled_M}\left(A=0.0015657565975999998\right)$$
R648BENZO2 + MO2→BENZO + HO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.000160791158292, B=365.0\right)$$
R649MO2 + BZCO3→BENZO2 + HO2 + CO2 + CH2O$$\mathrm{arrhenius_M}\left(A=0.0016079115829200003, B=365.0\right)$$
R650AROMP4 + OH→0.6 GLYX + 0.25 CO + 0.45 RCOOH + 0.33 RCO3 + 0.33 HO2 + 0.25 HCOOH + 0.25 OH$$\mathrm{scaled_M}\left(A=0.030110703800000003\right)$$
R651O3 + AROMP4→0.6 GLYX + 0.5 CO + 0.9 GLYC + 0.1 HO2 + 0.5 HCOOH + 0.1 OH$$\mathrm{scaled_M}\left(A=4.817712608 \times 10^{-7}\right)$$
R652AROMP4→0.2 GLYX + 1.2 RCHO + 0.2 HO2$$0.0015$$
R653AROMP5 + OH→0.25 CO + 0.52 RCOOH + 0.33 RCO3 + 0.6 MGLY + 0.33 HO2 + 0.15 ACTA + 0.1 HCOOH + 0.25 OH$$\mathrm{scaled_M}\left(A=0.030110703800000003\right)$$
R654O3 + AROMP5→0.5 CO + 0.95 GLYC + 0.6 MGLY + 0.1 HO2 + 0.3 ACTA + 0.2 HCOOH + 0.1 OH$$\mathrm{scaled_M}\left(A=4.817712608 \times 10^{-7}\right)$$
R655AROMP5→1.2 RCHO + 0.2 R4O2 + 0.2 MGLY + 0.2 HO2$$0.0015$$
R656BRO2 + HO2→LBRO2H + HO2$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=700.0\right)$$
R657NO + BRO2→NO + LBRO2N$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=350.0\right)$$
R658TRO2 + HO2→LTRO2H + HO2$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=700.0\right)$$
R659NO + TRO2→LTRO2N + NO$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=350.0\right)$$
R660XRO2 + HO2→LXRO2H + HO2$$\mathrm{arrhenius_M}\left(A=0.0008430997064000001, B=700.0\right)$$
R661NO + XRO2→NO + LXRO2N$$\mathrm{arrhenius_M}\left(A=0.0015657565976, B=350.0\right)$$
R662MO2 + NO3→NO2 + HO2 + CH2O$$\mathrm{scaled_M}\left(A=0.0007226568912\right)$$
R663O3→O2 + O$$j_{2}$$
R664O3→O1D + O2$$j_{3}$$
R665O2→2 O$$j_{1}$$
R666NO2→NO + O$$j_{11}$$
R667H2O2→2 OH$$j_{9}$$
R668MP→HO2 + OH + CH2O$$j_{10}$$
R669CH2O→CO + HO2 + H$$j_{7}$$
R670CH2O→CO + H2$$j_{8}$$
R671HNO3→NO2 + OH$$j_{16}$$
R672HNO2→NO + OH$$j_{15}$$
R673HNO4→NO3 + OH$$j_{17}$$
R674HNO4→NO2 + HO2$$j_{18}$$
R675NO3→NO2 + O$$j_{12}$$
R676NO3→NO + O2$$j_{13}$$
R677N2O5→NO3 + NO2$$j_{14}$$
R678ALD2→0.88 CO + 0.88 MO2 + 0.12 MCO3 + HO2$$j_{61}$$
R679ALD2→CO + CH4$$j_{62}$$
R680PAN→0.7 MCO3 + 0.3 MO2 + 0.3 NO3 + 0.7 NO2$$j_{59}$$
R681RCHO→CO + 0.07 A3O2 + 0.27 B3O2 + HO2 + 0.5 OTHRO2$$j_{70}$$
R682ACET→MCO3 + MO2$$j_{76}$$
R683ACET→CO + 2 MO2$$j_{77}$$
R684MEK→0.06 A3O2 + 0.85 MCO3 + 0.15 MO2 + 0.15 RCO3 + 0.23 B3O2 + 0.425 OTHRO2$$j_{69}$$
R685GLYC→CO + 1.73 HO2 + 0.07 OH + 0.9 CH2O + 0.1 MOH$$j_{68}$$
R686GLYX→2 CO + 2 HO2$$j_{72}$$
R687GLYX→2 CO + H2$$j_{73}$$
R688GLYX→CO + CH2O$$j_{74}$$
R689MGLY→CO + MCO3 + HO2$$j_{71}$$
R690MVK→CO + PRPE$$j_{63}$$
R691MVK→CO + MCO3 + HO2 + CH2O$$j_{64}$$
R692MVK→MO2 + RCO3$$j_{65}$$
R693MACR→CO + MCO3 + HO2 + CH2O$$j_{66}$$
R694HAC→MCO3 + HO2 + CH2O$$j_{75}$$
R695PRPN→RCHO + NO2 + HO2 + OH$$j_{79}$$
R696ETP→ALD2 + HO2 + OH$$j_{80}$$
R697RA3P→RCHO + HO2 + OH$$j_{81}$$
R698RB3P→ACET + HO2 + OH$$j_{82}$$
R699R4P→RCHO + HO2 + OH$$j_{83}$$
R700PP→ALD2 + HO2 + OH + CH2O$$j_{84}$$
R701RP→ALD2 + HO2 + OH$$j_{85}$$
R702R4N2→0.05 A3O2 + 0.32 ACET + 0.19 MEK + 0.18 MO2 + 0.32 ALD2 + 0.13 RCHO + NO2 + 0.18 B3O2 + 0.27 HO2 + 0.32 OTHRO2$$j_{98}$$
R703MAP→MO2 + OH$$j_{99}$$
R704Br2→2 Br$$j_{23}$$
R705BrO→Br + O$$j_{28}$$
R706HOBr→Br + OH$$j_{32}$$
R707BrNO3→Br + NO3$$j_{29}$$
R708BrNO3→BrO + NO2$$j_{30}$$
R709BrNO2→Br + NO2$$j_{31}$$
R710CHBr3→3 Br$$j_{56}$$
R711CH2Br2→2 Br$$j_{55}$$
R712CH3Br→MO2 + Br$$j_{50}$$
R713CH3Cl→MO2 + Cl$$j_{43}$$
R714CH2Cl2→2 Cl$$j_{45}$$
R715BrCl→Br + Cl$$j_{33}$$
R716Cl2→2 Cl$$j_{22}$$
R717ClO→Cl + O$$j_{27}$$
R718OClO→ClO + O$$j_{25}$$
R719Cl2O2→Cl + ClOO$$j_{26}$$
R720ClNO2→NO2 + Cl$$j_{21}$$
R721ClNO3→NO3 + Cl$$j_{19}$$
R722ClNO3→ClO + NO2$$j_{20}$$
R723HOCl→OH + Cl$$j_{24}$$
R724CH3CCl3→3 Cl$$j_{44}$$
R725CCl4→4 Cl$$j_{42}$$
R726CFC11→3 Cl$$j_{37}$$
R727CFC12→2 Cl$$j_{38}$$
R728CFC113→3 Cl$$j_{39}$$
R729CFC114→2 Cl$$j_{40}$$
R730CFC115→Cl$$j_{41}$$
R731HCFC123→2 Cl$$j_{47}$$
R732HCFC141b→2 Cl$$j_{48}$$
R733HCFC142b→Cl$$j_{49}$$
R734HCFC22→Cl$$j_{46}$$
R735H1301→Br$$j_{53}$$
R736H1211→Br + Cl$$j_{51}$$
R737H2402→2 Br$$j_{54}$$
R738ClOO→Cl + O2$$j_{101}$$
R739I2→2 I$$j_{114}$$
R740HOI→I + OH$$j_{115}$$
R741IO→I + O$$j_{116}$$
R742OIO→I + O2$$j_{117}$$
R743INO→NO + I$$j_{118}$$
R744IONO→I + NO2$$j_{119}$$
R745IONO2→I + NO3$$j_{120}$$
R746I2O2→I + OIO$$j_{121}$$
R747CH3I→I$$j_{122}$$
R748CH2I2→2 I$$j_{123}$$
R749CH2ICl→I + Cl$$j_{124}$$
R750CH2IBr→I + Br$$j_{125}$$
R751I2O4→2 OIO$$j_{126}$$
R752I2O3→IO + OIO$$j_{127}$$
R753IBr→I + Br$$j_{128}$$
R754ICl→I + Cl$$j_{129}$$
R755MPN→NO3 + HO2 + CH2O$$j_{103}$$
R756MPN→MO2 + NO2$$j_{104}$$
R757ATOOH→MCO3 + OH + CH2O$$j_{97}$$
R758N2O→O1D + N2$$j_{36}$$
R759OCS→CO + SO2$$j_{34}$$
R760SO4→SO2 + 2 OH$$j_{100}$$
R761NO→N + O$$j_{6}$$
R762PIP→RCHO + HO2 + OH$$j_{105}$$
R763ETHLN→CO + NO2 + HO2 + CH2O$$j_{107}$$
R764MONITS→MEK + NO2$$j_{111}$$
R765MONITU→RCHO + NO2$$j_{112}$$
R766HONIT→NO2 + HAC$$j_{113}$$
R767NITs→HNO2$$j_{130}$$
R768NITs→NO2$$j_{131}$$
R769NIT→HNO2$$j_{132}$$
R770NIT→NO2$$j_{133}$$
R771MENO3→NO2 + HO2 + CH2O$$j_{134}$$
R772ETNO3→ALD2 + NO2 + HO2$$j_{135}$$
R773IPRNO3→ACET + NO2 + HO2$$j_{136}$$
R774NPRNO3→RCHO + NO2 + HO2$$j_{137}$$
R775HMHP→2 OH + CH2O$$j_{86}$$
R776HPETHNL→CO + HO2 + OH + CH2O$$j_{87}$$
R777PYAC→MCO3 + HO2 + CO2$$j_{88}$$
R778PROPNN→MCO3 + NO2 + CH2O$$j_{89}$$
R779MVKHC→CO + MCO3 + HO2 + CH2O$$j_{90}$$
R780MVKHCB→0.5 GLYX + 0.5 CO + 0.5 MCO3 + 0.5 MGLY + 1.5 HO2$$j_{91}$$
R781MVKHP→0.53 MCO3 + 0.53 GLYC + 0.47 MGLY + 0.47 HO2 + OH + 0.47 CH2O$$j_{92}$$
R782MVKPC→0.429 GLYX + 0.571 CO + 0.429 MCO3 + 0.571 MGLY + 0.571 HO2 + OH$$j_{93}$$
R783MCRENOL→0.125 GLYX + 0.875 CO + 0.75 PYAC + 0.125 MCO3 + 0.125 MGLY + 0.125 HO2 + 1.75 OH$$j_{94}$$
R784MCRHP→0.77 CO + 0.23 MGLY + HO2 + OH + 0.77 HAC + 0.23 CH2O$$j_{95}$$
R785MACR1OOH→0.25 MACR1OOH + 0.488 MO2 + 0.262 MCO3 + 1.238 CO2 + 0.75 OH + 0.75 CH2O$$j_{96}$$
R786MVKN→1.01 MCO3 + 0.69 GLYC + 0.7 NO2 + 0.29 HO2 + 0.01 OH + 0.3 ETHLN$$j_{108}$$
R787MCRHN→CO + NO2 + HO2 + HAC$$j_{109}$$
R788MCRHNB→CO + PROPNN + HO2 + OH$$j_{110}$$
R789RIPA→MVK + HO2 + OH + CH2O$$j_{138}$$
R790RIPB→HO2 + MACR + OH + CH2O$$j_{139}$$
R791RIPC→HO2 + HC5A + OH$$j_{140}$$
R792RIPD→HO2 + HC5A + OH$$j_{141}$$
R793HPALD1→0.112 MVKPC + 0.888 CO + 0.224 C4HVP1 + 0.112 HO2 + 1.662 OH + 0.552 MCRENOL + 0.112 IDC$$j_{142}$$
R794HPALD2→0.182 MVKPC + 0.818 CO + 0.182 C4HVP2 + 0.182 HO2 + 1.637 OH + 0.455 MCRENOL + 0.182 IDC$$j_{143}$$
R795HPALD3→CO + MVK + HO2 + OH$$j_{144}$$
R796HPALD4→CO + HO2 + MACR + OH$$j_{145}$$
R797IHN1→0.55 CO + 0.55 MVKHP + NO2 + 0.45 HO2 + 0.45 HC5A + 0.55 OH$$j_{146}$$
R798IHN2→MVK + NO2 + HO2 + CH2O$$j_{147}$$
R799IHN3→NO2 + HO2 + MACR + CH2O$$j_{148}$$
R800IHN4→0.55 CO + NO2 + 0.45 HO2 + 0.45 HC5A + 0.55 OH + 0.55 MCRHP$$j_{149}$$
R801INPB→0.903 MVK + NO2 + 0.33 HO2 + 0.097 MACR + 0.67 OH + CH2O$$j_{150}$$
R802INPD→0.841 INA + 0.159 ICN + 0.159 HO2 + OH$$j_{151}$$
R803INPD→0.159 IHOO4 + 0.841 IHOO1 + NO2$$j_{152}$$
R804ICN→0.162 MVKPC + 0.839 CO + 0.128 C4HVP2 + 0.068 C4HVP1 + NO2 + 0.161 HO2 + 0.645 OH + 0.481 MCRENOL + 0.161 IDC$$j_{106}$$
R805IDN→0.05 MVK + 0.5 GLYC + 1.555 NO2 + 0.227 INA + 0.228 ICN + 0.005 MACR + 0.228 HO2 + 0.5 HAC + 0.055 CH2O$$j_{78}$$
R806ICPDH→0.15 MCRDH + CO + 0.35 MVKDH + 1.5 HO2 + 0.5 OH + 0.5 MCRHP$$j_{153}$$
R807ICPDH→0.438 GLYX + 0.122 CO + 0.122 MCRDH + 0.088 GLYC + 0.1 MVKHCB + 0.088 MGLY + HO2 + OH + 0.1 CH2O + 0.438 HAC$$j_{154}$$
R808IDHDP→0.75 ICPDH + 0.25 GLYC + 0.75 HO2 + 1.25 OH + 0.25 HAC$$j_{155}$$
R809IDHPE→0.571 GLYX + 0.429 GLYC + 0.429 MGLY + HO2 + OH + 0.571 HAC$$j_{156}$$
R810IDCHP→0.454 MVKPC + CO + 0.391 MVKHC + 0.155 MVKHCB + 1.454 HO2 + 0.546 OH$$j_{157}$$
R811ITHN→0.15 ETHLN + 0.05 MVKN + 0.5 MCRHN + 0.3 GLYC + 0.3 NO2 + 0.7 HO2 + OH + 0.55 CH2O + 0.45 HAC$$j_{158}$$
R812ITHN→0.15 MCRHP + 0.05 ATOOH + 0.5 HPETHNL + 0.35 GLYC + NO2 + 0.7 HO2 + 0.3 OH + 0.8 HAC + 0.15 CH2O$$j_{159}$$
R813ITCN→GLYC + NO2 + MGLY + OH$$j_{160}$$
R814ITCN→CO + 0.5 MVKHP + NO2 + HO2 + 0.5 MCRHP$$j_{161}$$
R815ETHP→ETO + OH$$j_{162}$$
R816BALD→BENZO2 + CO + HO2$$j_{163}$$
R817BZCO3H→BENZO2 + CO2 + OH$$j_{164}$$
R818BENZP→BENZO$$j_{165}$$
R819NPHEN→HNO2 + CO + HO2 + CO2 + AROMP4$$j_{166}$$

Analyses

default_run_24h

24-hour integration of the 819-reaction GEOS-Chem fullchem mechanism from a polluted-urban initial state (T=298 K, num_density=40.9 mol/m^3, NO=10 ppb, NO2=20 ppb, ISOP=2 ppb, O3=70 ppb) with constant noon-rate NO2 photolysis (j_11=0.0149 1/s). Plots O3, NO, NO2 and OH vs time over the full diurnal window. After mdl-5xp routed render_example_plots through earthsci_ast.simulation.simulate (the canonical Python ESS runner), LSODA on the cse-compiled rhs handles the 24-h window in ~3-4 min wall on the workspace machine after the per-component compile cache (~80-130 s) is warm; the integrator’s adaptive timestep grows large once the HOx/NOx cycle reaches its photostationary balance, so wall cost grows sub-linearly with window length.

Time span: 0 → 86400

O3 over 24 h of polluted-urban photochemistry under constant-noon photolysis. Initial fast drift settles into a slow net production driven by VOC (ISOP) oxidation; the diurnal-mean drift is the canonical signature of a stand-alone fullchem run with no diurnally-varying j-rates.

NO over 24 h — NO2+hv→NO+O3P competes against NO+O3→NO2 and NO+HO2/RO2 pathways; the NO/NO2 partition equilibrates fast and then drifts with the slower O3 budget.

NO2 over 24 h — depleted by photolysis, replenished by NO+O3 and HO2/RO2+NO; the partner of the NO trace under the fast NOx photostationary cycle.

OH over 24 h — sits in the HOx photostationary state set by the j_11/O3/H2O budget on a sub-second timescale, then drifts with the slow O3/HCHO/CO budgets over the diurnal window.

jNO2_photolysis_sweep

NO2-photolysis sensitivity at fixed polluted-urban initial composition (T=298 K, NO=10 ppb, NO2=20 ppb, ISOP=2 ppb, O3=70 ppb). Sweeps j_11 (the GEOS-Chem j-table index for NO2+hv → NO + O3P, see GasChem.jl/src/geoschem_fullchem.jl:3014) from dark (0 s^-1) through bright noon (~0.02 s^-1) on the same 8-grid superfast uses, integrates each grid point for 1800 s (30 min — long enough that the slow O3 budget responds to the sweep), then plots the t=1800 s OH and O3 against j_11. The HOx subsystem equilibrates on ≪ 1 s and OH tracks the photostationary value across the sweep; the O3 curve at 30 min captures the j_11 sensitivity of the net O3 photoproduction and is the canonical readout the bead acceptance asks for. Window choice is a wall-time/equilibration trade-off (mdl-1yv): longer windows than 30 min cost a near-proportional amount more wall in solve_ivp without materially changing the curve shape.

Time span: 0 → 1800

Swept over: j_11

Quasi-steady-state OH at t=1800 s vs NO2 photolysis rate j_11.

O3 at t=1800 s vs NO2 photolysis rate j_11 — quasi-steady-state ozone response across the dark-to-noon photolysis range.

temperature_sweep

Tropospheric-temperature sensitivity at fixed polluted-urban composition and noon photolysis (j_11=0.0149 1/s). Sweeps T across the same 9-grid superfast uses (240 K cold upper-troposphere → 320 K warm boundary layer) and integrates each grid point for 1800 s (30 min — long enough for the slow O3 budget to respond), then plots the t=1800 s OH and O3 against T. The bimolecular Arrhenius rates and termolecular falloff rates that dominate the HOx, NOx and O3 budgets all carry strong T dependence; the 30-min window lets the net effect on tropospheric O3 emerge in a single curve. Note: num_density is held at 40.9 mol/m³ (the polluted_urban value) rather than scaling with T at fixed P, so the sweep isolates the rate-coefficient T dependence from the P/T density dependence.

Time span: 0 → 1800

Swept over: T

Quasi-steady-state OH at t=1800 s vs temperature T.

O3 at t=1800 s vs temperature T — quasi-steady-state ozone response across the cold-troposphere-to-warm-boundary-layer range.

Raw .esm

Raw .esm JSON (this component)
{
  "tests": [
    {
      "id": "clean_troposphere",
      "description": "Clean troposphere reference state (mdl-ode): T=285 K, P=101325 Pa (num_density=42.76 mol/m^3), daytime photolysis (j_NO2≈0.005 1/s), low NOx ([NO]=50 ppt, [NO2]=200 ppt), low VOC ([ISOP]=200 ppt), background O3=30 ppb. Expected values from GasChem.jl/GEOSChemGasPhase via scripts/migrations/reference_values_geoschem_fullchem.jl.\n\nTolerance rationale (rel=1e-3): GEOS-Chem fullchem (~819 reactions) — 1e-3 absorbs Rosenbrock23 (Julia upstream) ↔ LSODA (Python ESS, cse=False per mdl-w1j to dodge the lambdify memory cliff) integrator-truncation gap over 600 s of stiff tropospheric chemistry. Tighter bands fail on radicals (OH, HO2) where step-size adaptation diverges between solvers.",
      "initial_conditions": {
        "NO": 0.05,
        "O3": 30,
        "ISOP": 0.2,
        "NO2": 0.2,
        "HO2": 4e-06,
        "OH": 4e-06
      },
      "parameter_overrides": {
        "T": 285.0,
        "j_11": 0.005,
        "num_density": 42.76236658521454
      },
      "time_span": {
        "start": 0.0,
        "end": 600.0
      },
      "tolerance": {
        "rel": 0.001
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      "assertions": [
        {
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          "time": 60,
          "variable": "O3"
        },
        {
          "expected": 30.059782891958424,
          "time": 300,
          "variable": "O3"
        },
        {
          "expected": 30.081351650954094,
          "time": 600,
          "variable": "O3"
        },
        {
          "expected": 0.056261292743874675,
          "time": 60,
          "variable": "NO"
        },
        {
          "expected": 0.06895299789814631,
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          "variable": "NO"
        },
        {
          "expected": 0.07080376502914437,
          "time": 600,
          "variable": "NO"
        },
        {
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          "variable": "NO2"
        },
        {
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          "time": 300,
          "variable": "NO2"
        },
        {
          "expected": 0.18393323047892784,
          "time": 600,
          "variable": "NO2"
        },
        {
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          "time": 60,
          "variable": "OH"
        },
        {
          "expected": 4.306079890618432e-05,
          "time": 300,
          "variable": "OH"
        },
        {
          "expected": 2.952345186177213e-05,
          "time": 600,
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        {
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          "time": 60,
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        {
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          "time": 300,
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        },
        {
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          "time": 600,
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        },
        {
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          "time": 60,
          "variable": "HNO3"
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        {
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          "time": 300,
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        {
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        {
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        {
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        {
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        {
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        },
        {
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          "time": 300,
          "variable": "ISOP"
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        {
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          "time": 600,
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        },
        {
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          "variable": "CH2O"
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        {
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        {
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        }
      ]
    },
    {
      "id": "polluted_urban",
      "description": "Polluted urban reference state (mdl-ode): T=298 K, P=101325 Pa (num_density=40.89 mol/m^3), daytime (j_NO2≈0.0149 1/s), high NOx ([NO]=10 ppb, [NO2]=20 ppb), high VOC ([ISOP]=2 ppb), elevated O3=70 ppb. Expected values from GasChem.jl/GEOSChemGasPhase via scripts/migrations/reference_values_geoschem_fullchem.jl.\n\nTolerance rationale (rel=1e-3): see clean_troposphere — same Rosenbrock23 (Julia) ↔ LSODA (Python, cse=False per mdl-w1j) gap, applied to the high-NOx/high-VOC stiff regime where photochemical-smog cycling amplifies step-size-adaptation drift on radicals.",
      "initial_conditions": {
        "NO": 10,
        "O3": 70,
        "ISOP": 2,
        "NO2": 20,
        "HO2": 4e-06,
        "OH": 4e-06
      },
      "parameter_overrides": {
        "T": 298.0,
        "j_11": 0.0149,
        "num_density": 40.896894217403165
      },
      "time_span": {
        "start": 0.0,
        "end": 600.0
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      "tolerance": {
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          "time": 60,
          "variable": "O3"
        },
        {
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          "time": 300,
          "variable": "O3"
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        {
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          "time": 600,
          "variable": "O3"
        },
        {
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          "time": 60,
          "variable": "NO"
        },
        {
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          "time": 300,
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        },
        {
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          "time": 600,
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        },
        {
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          "time": 60,
          "variable": "NO2"
        },
        {
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          "time": 300,
          "variable": "NO2"
        },
        {
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          "time": 600,
          "variable": "NO2"
        },
        {
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          "time": 60,
          "variable": "OH"
        },
        {
          "expected": 1.0206287503371786e-05,
          "time": 300,
          "variable": "OH"
        },
        {
          "expected": 9.94758541244481e-06,
          "time": 600,
          "variable": "OH"
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        {
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          "time": 60,
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        {
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          "time": 300,
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        {
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          "time": 600,
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        {
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          "time": 60,
          "variable": "HNO3"
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        {
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          "time": 300,
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        {
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          "time": 600,
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          "time": 60,
          "variable": "CO"
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          "time": 300,
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          "time": 600,
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        {
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          "time": 60,
          "variable": "ISOP"
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        {
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          "time": 300,
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        {
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          "time": 600,
          "variable": "ISOP"
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        {
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          "time": 60,
          "variable": "CH2O"
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        {
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          "time": 300,
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        {
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          "time": 600,
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      ]
    },
    {
      "id": "upper_troposphere",
      "description": "Upper-troposphere / lower-stratosphere reference state (mdl-ode): T=220 K, P=20000 Pa (num_density=10.94 mol/m^3, ~12 km), reduced photolysis (j_NO2≈0.002 1/s), low NOx, no VOCs, O3=100 ppb. Expected values from GasChem.jl/GEOSChemGasPhase via scripts/migrations/reference_values_geoschem_fullchem.jl.\n\nTolerance rationale (rel=1e-3): see clean_troposphere — same Rosenbrock23 (Julia) ↔ LSODA (Python, cse=False per mdl-w1j) gap. The cold/low-pressure regime exercises a different temperature/falloff branch of the rate-law expressions but the truncation profile is comparable.",
      "initial_conditions": {
        "NO": 0.05,
        "O3": 100,
        "ISOP": 0,
        "NO2": 0.1,
        "HO2": 4e-06,
        "OH": 4e-06
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      "parameter_overrides": {
        "T": 220.0,
        "j_11": 0.002,
        "num_density": 10.934458853631334
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      "time_span": {
        "start": 0.0,
        "end": 600.0
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      "tolerance": {
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      "assertions": [
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          "variable": "O3"
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        {
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          "time": 300,
          "variable": "O3"
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        {
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        {
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          "variable": "NO"
        },
        {
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          "time": 300,
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        },
        {
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          "time": 600,
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        },
        {
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          "time": 60,
          "variable": "NO2"
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        {
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          "time": 300,
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        {
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          "time": 600,
          "variable": "NO2"
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        {
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          "time": 300,
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        {
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          "time": 600,
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        {
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          "time": 60,
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        {
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          "time": 300,
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        {
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          "time": 600,
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        {
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          "time": 60,
          "variable": "HNO3"
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        {
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          "time": 300,
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        {
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        {
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          "time": 300,
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        {
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          "time": 600,
          "variable": "ISOP"
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        {
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        {
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          "time": 300,
          "variable": "CH2O"
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        {
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          "time": 600,
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  "reference": {
    "notes": "source_ref: GasChem.jl src/geoschem_fullchem.jl\nGEOS-Chem fullchem gas-phase mechanism (~819 reactions, ~272 species). Migrated from GasChem.jl GEOSChemGasPhase via mtk2esm with sub-system rate-law inlining.\n\nPost-process workarounds applied (mdl-ode):\n  - 64 max(expr, 0.0) rate clamps were rewritten to (a + abs(a))/2 by scripts/migrations/rewrite_max_in_esm.py because EarthSciASTCatalystExt._esm_to_symbolic does not accept the max op. File a follow-on bead in EarthSciAST to add max/min support and drop this stop-gap (same lifecycle as scripts/migrations/post_process_geoschem_fullchem.py).\n\nInline tests (mdl-ode): 3 pinned reference states (clean troposphere / polluted urban / upper troposphere) with expected species values from upstream GasChem.GEOSChemGasPhase via mtkcompile + Rosenbrock23. Generator: scripts/migrations/reference_values_geoschem_fullchem.jl. Cross-implementation tolerance rel=1e-3 (loose enough to absorb solver-tolerance and Catalyst path divergence between rxn_sys=false and the migrated flat ReactionSystem; tight enough to catch translation bugs). Reference timing on the workspace machine: GasChem build (rxn_sys=false, ODE-model path) = 1138 s, mtkcompile = 65.6 s, peak RSS during build ~8.2 GiB — inside the bead's combined 60-min / 32-GiB budget. The migration kept num_density (mol/m³) but not P; tests override num_density = P / (R_GAS · T) per state to maintain (T, P) consistency with the bead-pinned states."
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          "species": "HO2"
        },
        {
          "stoichiometry": 0.645,
          "species": "OH"
        },
        {
          "stoichiometry": 0.481,
          "species": "MCRENOL"
        },
        {
          "stoichiometry": 0.161,
          "species": "IDC"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "IDN"
        }
      ],
      "id": "R805",
      "rate": "j_78",
      "products": [
        {
          "stoichiometry": 0.05,
          "species": "MVK"
        },
        {
          "stoichiometry": 0.5,
          "species": "GLYC"
        },
        {
          "stoichiometry": 1.555,
          "species": "NO2"
        },
        {
          "stoichiometry": 0.227,
          "species": "INA"
        },
        {
          "stoichiometry": 0.228,
          "species": "ICN"
        },
        {
          "stoichiometry": 0.005,
          "species": "MACR"
        },
        {
          "stoichiometry": 0.228,
          "species": "HO2"
        },
        {
          "stoichiometry": 0.5,
          "species": "HAC"
        },
        {
          "stoichiometry": 0.055,
          "species": "CH2O"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ICPDH"
        }
      ],
      "id": "R806",
      "rate": "j_153",
      "products": [
        {
          "stoichiometry": 0.15,
          "species": "MCRDH"
        },
        {
          "stoichiometry": 1,
          "species": "CO"
        },
        {
          "stoichiometry": 0.35,
          "species": "MVKDH"
        },
        {
          "stoichiometry": 1.5,
          "species": "HO2"
        },
        {
          "stoichiometry": 0.5,
          "species": "OH"
        },
        {
          "stoichiometry": 0.5,
          "species": "MCRHP"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ICPDH"
        }
      ],
      "id": "R807",
      "rate": "j_154",
      "products": [
        {
          "stoichiometry": 0.438,
          "species": "GLYX"
        },
        {
          "stoichiometry": 0.122,
          "species": "CO"
        },
        {
          "stoichiometry": 0.122,
          "species": "MCRDH"
        },
        {
          "stoichiometry": 0.088,
          "species": "GLYC"
        },
        {
          "stoichiometry": 0.1,
          "species": "MVKHCB"
        },
        {
          "stoichiometry": 0.088,
          "species": "MGLY"
        },
        {
          "stoichiometry": 1,
          "species": "HO2"
        },
        {
          "stoichiometry": 1,
          "species": "OH"
        },
        {
          "stoichiometry": 0.1,
          "species": "CH2O"
        },
        {
          "stoichiometry": 0.438,
          "species": "HAC"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "IDHDP"
        }
      ],
      "id": "R808",
      "rate": "j_155",
      "products": [
        {
          "stoichiometry": 0.75,
          "species": "ICPDH"
        },
        {
          "stoichiometry": 0.25,
          "species": "GLYC"
        },
        {
          "stoichiometry": 0.75,
          "species": "HO2"
        },
        {
          "stoichiometry": 1.25,
          "species": "OH"
        },
        {
          "stoichiometry": 0.25,
          "species": "HAC"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "IDHPE"
        }
      ],
      "id": "R809",
      "rate": "j_156",
      "products": [
        {
          "stoichiometry": 0.571,
          "species": "GLYX"
        },
        {
          "stoichiometry": 0.429,
          "species": "GLYC"
        },
        {
          "stoichiometry": 0.429,
          "species": "MGLY"
        },
        {
          "stoichiometry": 1,
          "species": "HO2"
        },
        {
          "stoichiometry": 1,
          "species": "OH"
        },
        {
          "stoichiometry": 0.571,
          "species": "HAC"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "IDCHP"
        }
      ],
      "id": "R810",
      "rate": "j_157",
      "products": [
        {
          "stoichiometry": 0.454,
          "species": "MVKPC"
        },
        {
          "stoichiometry": 1,
          "species": "CO"
        },
        {
          "stoichiometry": 0.391,
          "species": "MVKHC"
        },
        {
          "stoichiometry": 0.155,
          "species": "MVKHCB"
        },
        {
          "stoichiometry": 1.454,
          "species": "HO2"
        },
        {
          "stoichiometry": 0.546,
          "species": "OH"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ITHN"
        }
      ],
      "id": "R811",
      "rate": "j_158",
      "products": [
        {
          "stoichiometry": 0.15,
          "species": "ETHLN"
        },
        {
          "stoichiometry": 0.05,
          "species": "MVKN"
        },
        {
          "stoichiometry": 0.5,
          "species": "MCRHN"
        },
        {
          "stoichiometry": 0.3,
          "species": "GLYC"
        },
        {
          "stoichiometry": 0.3,
          "species": "NO2"
        },
        {
          "stoichiometry": 0.7,
          "species": "HO2"
        },
        {
          "stoichiometry": 1,
          "species": "OH"
        },
        {
          "stoichiometry": 0.55,
          "species": "CH2O"
        },
        {
          "stoichiometry": 0.45,
          "species": "HAC"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ITHN"
        }
      ],
      "id": "R812",
      "rate": "j_159",
      "products": [
        {
          "stoichiometry": 0.15,
          "species": "MCRHP"
        },
        {
          "stoichiometry": 0.05,
          "species": "ATOOH"
        },
        {
          "stoichiometry": 0.5,
          "species": "HPETHNL"
        },
        {
          "stoichiometry": 0.35,
          "species": "GLYC"
        },
        {
          "stoichiometry": 1,
          "species": "NO2"
        },
        {
          "stoichiometry": 0.7,
          "species": "HO2"
        },
        {
          "stoichiometry": 0.3,
          "species": "OH"
        },
        {
          "stoichiometry": 0.8,
          "species": "HAC"
        },
        {
          "stoichiometry": 0.15,
          "species": "CH2O"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ITCN"
        }
      ],
      "id": "R813",
      "rate": "j_160",
      "products": [
        {
          "stoichiometry": 1,
          "species": "GLYC"
        },
        {
          "stoichiometry": 1,
          "species": "NO2"
        },
        {
          "stoichiometry": 1,
          "species": "MGLY"
        },
        {
          "stoichiometry": 1,
          "species": "OH"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ITCN"
        }
      ],
      "id": "R814",
      "rate": "j_161",
      "products": [
        {
          "stoichiometry": 1,
          "species": "CO"
        },
        {
          "stoichiometry": 0.5,
          "species": "MVKHP"
        },
        {
          "stoichiometry": 1,
          "species": "NO2"
        },
        {
          "stoichiometry": 1,
          "species": "HO2"
        },
        {
          "stoichiometry": 0.5,
          "species": "MCRHP"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "ETHP"
        }
      ],
      "id": "R815",
      "rate": "j_162",
      "products": [
        {
          "stoichiometry": 1,
          "species": "ETO"
        },
        {
          "stoichiometry": 1,
          "species": "OH"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "BALD"
        }
      ],
      "id": "R816",
      "rate": "j_163",
      "products": [
        {
          "stoichiometry": 1,
          "species": "BENZO2"
        },
        {
          "stoichiometry": 1,
          "species": "CO"
        },
        {
          "stoichiometry": 1,
          "species": "HO2"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "BZCO3H"
        }
      ],
      "id": "R817",
      "rate": "j_164",
      "products": [
        {
          "stoichiometry": 1,
          "species": "BENZO2"
        },
        {
          "stoichiometry": 1,
          "species": "CO2"
        },
        {
          "stoichiometry": 1,
          "species": "OH"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "BENZP"
        }
      ],
      "id": "R818",
      "rate": "j_165",
      "products": [
        {
          "stoichiometry": 1,
          "species": "BENZO"
        }
      ]
    },
    {
      "substrates": [
        {
          "stoichiometry": 1,
          "species": "NPHEN"
        }
      ],
      "id": "R819",
      "rate": "j_166",
      "products": [
        {
          "stoichiometry": 1,
          "species": "HNO2"
        },
        {
          "stoichiometry": 1,
          "species": "CO"
        },
        {
          "stoichiometry": 1,
          "species": "HO2"
        },
        {
          "stoichiometry": 1,
          "species": "CO2"
        },
        {
          "stoichiometry": 1,
          "species": "AROMP4"
        }
      ]
    }
  ],
  "species": {
    "RIPB": {
      "default": 0
    },
    "MVKOHOO": {
      "default": 0
    },
    "IHN4": {
      "default": 0
    },
    "CFC113": {
      "default": 0
    },
    "LTRO2H": {
      "default": 0
    },
    "IDHNDOO1": {
      "default": 0
    },
    "HCFC123": {
      "default": 0
    },
    "CH2I2": {
      "default": 0
    },
    "N2O5": {
      "default": 4e-06
    },
    "IBr": {
      "default": 0
    },
    "XRO2": {
      "default": 0
    },
    "CHCl3": {
      "default": 0
    },
    "SALCCL": {
      "default": 0
    },
    "MONITA": {
      "default": 0
    },
    "ETP": {
      "default": 0
    },
    "NO": {
      "default": 0.0004
    },
    "PYAC": {
      "default": 0
    },
    "CH4": {
      "default": 1800
    },
    "C2H6": {
      "default": 0
    },
    "CHBr3": {
      "default": 0
    },
    "C2H2": {
      "default": 0
    },
    "ETNO3": {
      "default": 0
    },
    "HONIT": {
      "default": 0
    },
    "IO": {
      "default": 0
    },
    "RB3P": {
      "default": 0
    },
    "HOI": {
      "default": 0
    },
    "ISOP": {
      "default": 0
    },
    "C4HVP1": {
      "default": 0
    },
    "HPETHNL": {
      "default": 0
    },
    "ETOO": {
      "default": 0
    },
    "O1D": {
      "default": 1e-06
    },
    "RIPD": {
      "default": 0
    },
    "MACR": {
      "default": 0
    },
    "LISOPNO3": {
      "default": 0
    },
    "PRN1": {
      "default": 0
    },
    "H1211": {
      "default": 0
    },
    "PRPN": {
      "default": 0
    },
    "BrO": {
      "default": 0
    },
    "Br": {
      "default": 0
    },
    "C2H4": {
      "default": 0
    },
    "MENO3": {
      "default": 0
    },
    "PAN": {
      "default": 0
    },
    "IEPOXAOO": {
      "default": 0
    },
    "H": {
      "default": 0
    },
    "MCRENOL": {
      "default": 0
    },
    "R4N1": {
      "default": 0
    },
    "HMHP": {
      "default": 0
    },
    "IEPOXD": {
      "default": 0
    },
    "NRO2": {
      "default": 0
    },
    "B3O2": {
      "default": 0
    },
    "HO2": {
      "default": 4e-06
    },
    "OH": {
      "default": 4e-06
    },
    "CFC115": {
      "default": 0
    },
    "HI": {
      "default": 0
    },
    "RA3P": {
      "default": 0
    },
    "MONITU": {
      "default": 0
    },
    "IDC": {
      "default": 0
    },
    "LBRO2N": {
      "default": 0
    },
    "INA": {
      "default": 0
    },
    "H2O2": {
      "default": 4e-06
    },
    "CH2O": {
      "default": 4e-06
    },
    "CH2Br2": {
      "default": 0
    },
    "ClOO": {
      "default": 0
    },
    "MTPA": {
      "default": 0
    },
    "BALD": {
      "default": 0
    },
    "MO2": {
      "default": 4e-06
    },
    "IHPOO2": {
      "default": 0
    },
    "MACR1OO": {
      "default": 0
    },
    "CH2OO": {
      "default": 0
    },
    "HCFC22": {
      "default": 0
    },
    "BENZO": {
      "default": 0
    },
    "MVKN": {
      "default": 0
    },
    "CH2ICl": {
      "default": 0
    },
    "I2": {
      "default": 0
    },
    "CSL": {
      "default": 0
    },
    "CH3CCl3": {
      "default": 0
    },
    "I2O3": {
      "default": 0
    },
    "ICl": {
      "default": 0
    },
    "HBr": {
      "default": 0
    },
    "Cl2": {
      "default": 0
    },
    "XYLE": {
      "default": 0
    },
    "PPN": {
      "default": 0
    },
    "HNO2": {
      "default": 4e-06
    },
    "BZCO3": {
      "default": 0
    },
    "SO4": {
      "default": 0
    },
    "N2O": {
      "default": 300
    },
    "IHN2": {
      "default": 0
    },
    "LIMO": {
      "default": 0
    },
    "HCFC141b": {
      "default": 0
    },
    "MTPO": {
      "default": 0
    },
    "PHEN": {
      "default": 0
    },
    "RIPC": {
      "default": 0
    },
    "OTHRO2": {
      "default": 0
    },
    "ITCN": {
      "default": 0
    },
    "TOLU": {
      "default": 0
    },
    "A3O2": {
      "default": 0
    },
    "HPALD4": {
      "default": 0
    },
    "ICHOO": {
      "default": 0
    },
    "ETHP": {
      "default": 0
    },
    "BZCO3H": {
      "default": 0
    },
    "LXRO2H": {
      "default": 0
    },
    "H2O": {
      "default": 18400000
    },
    "AROMRO2": {
      "default": 0
    },
    "MGLY": {
      "default": 0
    },
    "MAP": {
      "default": 0
    },
    "LXRO2N": {
      "default": 0
    },
    "KO2": {
      "default": 0
    },
    "LTRO2N": {
      "default": 0
    },
    "Cl2O2": {
      "default": 0
    },
    "NPRNO3": {
      "default": 0
    },
    "IPRNO3": {
      "default": 0
    },
    "HNO3": {
      "default": 4e-06
    },
    "MCROHOO": {
      "default": 0
    },
    "LNRO2N": {
      "default": 0
    },
    "BRO2": {
      "default": 0
    },
    "ALK4": {
      "default": 0
    },
    "R4N2": {
      "default": 0
    },
    "INO2B": {
      "default": 0
    },
    "C4HVP2": {
      "default": 0
    },
    "PIO2": {
      "default": 0
    },
    "O3": {
      "default": 20
    },
    "BENZP": {
      "default": 0
    },
    "HPALD1": {
      "default": 0
    },
    "N": {
      "default": 4e-11
    },
    "LIMO2": {
      "default": 0
    },
    "IDHNDOO2": {
      "default": 0
    },
    "O2": {
      "constant": true,
      "default": 210000000
    },
    "CO": {
      "default": 100
    },
    "ICHE": {
      "default": 0
    },
    "IDHNBOO": {
      "default": 0
    },
    "I2O2": {
      "default": 0
    },
    "MCRDH": {
      "default": 0
    },
    "HCFC142b": {
      "default": 0
    },
    "PIP": {
      "default": 0
    },
    "BrCl": {
      "default": 0
    },
    "HCOOH": {
      "default": 0
    },
    "NIT": {
      "default": 0
    },
    "GLYX": {
      "default": 0
    },
    "HOCl": {
      "default": 0
    },
    "ICPDH": {
      "default": 0
    },
    "SALAAL": {
      "default": 1e-09,
      "description": "Held at 1e-9 rather than 0 as a denominator guard (mdl-79g): reaction R1's rate is k_mt1/SALAAL, so a 0 initial value makes the first RHS evaluation 0/0 and the whole RHS non-finite. SALAAL is also R1's own substrate, so the division cancels the mass-action factor and the term reduces to k_mt1*O3*SO2 -- the singularity is removable and any positive value collapses it. The value is inert here: SALAAL is produced by no reaction and consumed only through k_mt1..k_mt3, all of which default to 0. 1e-9 matches the seed the analyses in this file already use. Remove this default once the substrate-detection heuristic drop (mdl-79g) lands on EarthSciAST main and R1's division is gone."
    },
    "LNRO2H": {
      "default": 0
    },
    "RCO3": {
      "default": 0
    },
    "HMS": {
      "default": 1e-06
    },
    "ClNO3": {
      "default": 0
    },
    "PP": {
      "default": 0
    },
    "NITs": {
      "default": 0
    },
    "H1301": {
      "default": 0
    },
    "ACTA": {
      "default": 0
    },
    "NAP": {
      "default": 0
    },
    "IHPNBOO": {
      "default": 0
    },
    "IHPNDOO": {
      "default": 0
    },
    "ICNOO": {
      "default": 0
    },
    "HMML": {
      "default": 0
    },
    "IHPOO3": {
      "default": 0
    },
    "CO2": {
      "default": 355000
    },
    "I2O4": {
      "default": 0
    },
    "IEPOXA": {
      "default": 0
    },
    "MVKHP": {
      "default": 0
    },
    "CH3CHOO": {
      "default": 0
    },
    "ROH": {
      "default": 0
    },
    "PRPE": {
      "default": 0
    },
    "MPN": {
      "default": 0
    },
    "IHOO1": {
      "default": 0
    },
    "ICN": {
      "default": 0
    },
    "LBRO2H": {
      "default": 0
    },
    "IHN1": {
      "default": 0
    },
    "EOH": {
      "default": 0
    },
    "HPALD2": {
      "default": 0
    },
    "MCRHNB": {
      "default": 0
    },
    "MACRNO2": {
      "default": 0
    },
    "OClO": {
      "default": 0
    },
    "HPALD1OO": {
      "default": 0
    },
    "LVOC": {
      "default": 0
    },
    "HC5A": {
      "default": 0
    },
    "RIPA": {
      "default": 0
    },
    "IHPOO1": {
      "default": 0
    },
    "MACR1OOH": {
      "default": 0
    },
    "ALD2": {
      "default": 0
    },
    "CH3Cl": {
      "default": 0
    },
    "IDHDP": {
      "default": 0
    },
    "MSA": {
      "default": 0
    },
    "ATO2": {
      "default": 0
    },
    "H2402": {
      "default": 0
    },
    "HPALD3": {
      "default": 0
    },
    "ATOOH": {
      "default": 0
    },
    "IDN": {
      "default": 0
    },
    "OLND": {
      "default": 0
    },
    "NPHEN": {
      "default": 0
    },
    "C3H8": {
      "default": 0
    },
    "MCO3": {
      "default": 0
    },
    "MONITS": {
      "default": 0
    },
    "DMS": {
      "default": 0
    },
    "OIO": {
      "default": 0
    },
    "HNO4": {
      "default": 4e-06
    },
    "ClO": {
      "default": 0
    },
    "IONITA": {
      "default": 0
    },
    "ITHN": {
      "default": 0
    },
    "SO4s": {
      "default": 0
    },
    "OCS": {
      "default": 9e-06
    },
    "IONO2": {
      "default": 0
    },
    "ETHLN": {
      "default": 0
    },
    "RCHO": {
      "default": 0
    },
    "MCRHP": {
      "default": 0
    },
    "O": {
      "default": 0
    },
    "CFC114": {
      "default": 0
    },
    "MVK": {
      "default": 0
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                                  },
                                  {
                                    "args": [
                                      1.0,
                                      {
                                        "args": [
                                          {
                                            "args": [
                                              "Fc",
                                              "num_density"
                                            ],
                                            "op": "*"
                                          },
                                          {
                                            "args": [
                                              0.43,
                                              {
                                                "args": [
                                                  {
                                                    "args": [
                                                      298.0,
                                                      "T"
                                                    ],
                                                    "op": "/"
                                                  },
                                                  8
                                                ],
                                                "op": "^"
                                              }
                                            ],
                                            "op": "*"
                                          }
                                        ],
                                        "op": "/"
                                      }
                                    ],
                                    "op": "+"
                                  }
                                ],
                                "op": "/"
                              }
                            ],
                            "op": "+"
                          },
                          {
                            "args": [
                              1.0,
                              {
                                "args": [
                                  {
                                    "args": [
                                      "Fc",
                                      "num_density"
                                    ],
                                    "op": "*"
                                  },
                                  {
                                    "args": [
                                      0.43,
                                      {
                                        "args": [
                                          {
                                            "args": [
                                              298.0,
                                              "T"
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                                            "op": "/"
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                                          8
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                                        "op": "^"
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                                    ],
                                    "op": "*"
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                                ],
                                "op": "/"
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                            ],
                            "op": "+"
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                        ],
                        "op": "*"
                      }
                    ],
                    "op": "/"
                  }
                ]
              }
            ]
          },
          2.0
        ]
      }
    },
    "troe_M2_arr": {
      "params": [
        "A",
        "n_inf",
        "k0_300",
        "n_0"
      ],
      "body": {
        "args": [
          {
            "args": [
              "A",
              {
                "args": [
                  0.0
                ],
                "op": "exp"
              },
              {
                "args": [
                  {
                    "args": [
                      300,
                      "T"
                    ],
                    "op": "/"
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                  "n_inf"
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                "op": "^"
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              {
                "args": [
                  "num_density",
                  2
                ],
                "op": "^"
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              {
                "args": [
                  0.6,
                  {
                    "args": [
                      1.0,
                      {
                        "args": [
                          1.0,
                          {
                            "args": [
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                                "args": [
                                  {
                                    "args": [
                                      "k0_300",
                                      {
                                        "args": [
                                          {
                                            "args": [
                                              300,
                                              "T"
                                            ],
                                            "op": "/"
                                          },
                                          "n_0"
                                        ],
                                        "op": "^"
                                      },
                                      "num_density"
                                    ],
                                    "op": "*"
                                  }
                                ],
                                "op": "log10"
                              },
                              2
                            ],
                            "op": "^"
                          }
                        ],
                        "op": "+"
                      }
                    ],
                    "op": "/"
                  }
                ],
                "op": "^"
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            ],
            "op": "*"
          },
          {
            "args": [
              1.0,
              {
                "args": [
                  "k0_300",
                  {
                    "args": [
                      {
                        "args": [
                          300,
                          "T"
                        ],
                        "op": "/"
                      },
                      "n_0"
                    ],
                    "op": "^"
                  },
                  "num_density"
                ],
                "op": "*"
              }
            ],
            "op": "+"
          }
        ],
        "op": "/"
      }
    },
    "arrhenius_clamp_lin": {
      "params": [
        "B",
        "C"
      ],
      "body": {
        "op": "/",
        "args": [
          {
            "op": "+",
            "args": [
              {
                "args": [
                  0.000127669384112,
                  {
                    "args": [
                      "B",
                      {
                        "args": [
                          "C",
                          "T"
                        ],
                        "op": "*"
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                    ],
                    "op": "+"
                  },
                  {
                    "args": [
                      {
                        "args": [
                          1300.0,
                          "T"
                        ],
                        "op": "/"
                      }
                    ],
                    "op": "exp"
                  },
                  "num_density"
                ],
                "op": "*"
              },
              {
                "op": "abs",
                "args": [
                  {
                    "args": [
                      0.000127669384112,
                      {
                        "args": [
                          "B",
                          {
                            "args": [
                              "C",
                              "T"
                            ],
                            "op": "*"
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                        ],
                        "op": "+"
                      },
                      {
                        "args": [
                          {
                            "args": [
                              1300.0,
                              "T"
                            ],
                            "op": "/"
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                        ],
                        "op": "exp"
                      },
                      "num_density"
                    ],
                    "op": "*"
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                ]
              }
            ]
          },
          2.0
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    }
  },
  "analyses": [
    {
      "id": "default_run_24h",
      "description": "24-hour integration of the 819-reaction GEOS-Chem fullchem mechanism from a polluted-urban initial state (T=298 K, num_density=40.9 mol/m^3, NO=10 ppb, NO2=20 ppb, ISOP=2 ppb, O3=70 ppb) with constant noon-rate NO2 photolysis (j_11=0.0149 1/s). Plots O3, NO, NO2 and OH vs time over the full diurnal window. After mdl-5xp routed render_example_plots through earthsci_ast.simulation.simulate (the canonical Python ESS runner), LSODA on the cse-compiled rhs handles the 24-h window in ~3-4 min wall on the workspace machine after the per-component compile cache (~80-130 s) is warm; the integrator's adaptive timestep grows large once the HOx/NOx cycle reaches its photostationary balance, so wall cost grows sub-linearly with window length.",
      "time_span": {
        "start": 0,
        "end": 86400
      },
      "initial_state": {
        "NO": 10,
        "NO2": 20,
        "O3": 70,
        "ISOP": 2,
        "OH": 4e-06,
        "HO2": 4e-06
      },
      "parameters": {
        "T": 298.0,
        "num_density": 40.896894217403165,
        "j_11": 0.0149
      },
      "plots": [
        {
          "id": "O3_vs_time",
          "type": "line",
          "description": "O3 over 24 h of polluted-urban photochemistry under constant-noon photolysis. Initial fast drift settles into a slow net production driven by VOC (ISOP) oxidation; the diurnal-mean drift is the canonical signature of a stand-alone fullchem run with no diurnally-varying j-rates.",
          "x": {
            "variable": "t",
            "label": "time (s)"
          },
          "y": {
            "variable": "O3",
            "label": "O3 (ppb)"
          }
        },
        {
          "id": "NO_vs_time",
          "type": "line",
          "description": "NO over 24 h — NO2+hv→NO+O3P competes against NO+O3→NO2 and NO+HO2/RO2 pathways; the NO/NO2 partition equilibrates fast and then drifts with the slower O3 budget.",
          "x": {
            "variable": "t",
            "label": "time (s)"
          },
          "y": {
            "variable": "NO",
            "label": "NO (ppb)"
          }
        },
        {
          "id": "NO2_vs_time",
          "type": "line",
          "description": "NO2 over 24 h — depleted by photolysis, replenished by NO+O3 and HO2/RO2+NO; the partner of the NO trace under the fast NOx photostationary cycle.",
          "x": {
            "variable": "t",
            "label": "time (s)"
          },
          "y": {
            "variable": "NO2",
            "label": "NO2 (ppb)"
          }
        },
        {
          "id": "OH_vs_time",
          "type": "line",
          "description": "OH over 24 h — sits in the HOx photostationary state set by the j_11/O3/H2O budget on a sub-second timescale, then drifts with the slow O3/HCHO/CO budgets over the diurnal window.",
          "x": {
            "variable": "t",
            "label": "time (s)"
          },
          "y": {
            "variable": "OH",
            "label": "OH (ppb)"
          }
        }
      ]
    },
    {
      "id": "jNO2_photolysis_sweep",
      "description": "NO2-photolysis sensitivity at fixed polluted-urban initial composition (T=298 K, NO=10 ppb, NO2=20 ppb, ISOP=2 ppb, O3=70 ppb). Sweeps j_11 (the GEOS-Chem j-table index for NO2+hv → NO + O3P, see GasChem.jl/src/geoschem_fullchem.jl:3014) from dark (0 s^-1) through bright noon (~0.02 s^-1) on the same 8-grid superfast uses, integrates each grid point for 1800 s (30 min — long enough that the slow O3 budget responds to the sweep), then plots the t=1800 s OH and O3 against j_11. The HOx subsystem equilibrates on ≪ 1 s and OH tracks the photostationary value across the sweep; the O3 curve at 30 min captures the j_11 sensitivity of the net O3 photoproduction and is the canonical readout the bead acceptance asks for. Window choice is a wall-time/equilibration trade-off (mdl-1yv): longer windows than 30 min cost a near-proportional amount more wall in solve_ivp without materially changing the curve shape.",
      "time_span": {
        "start": 0,
        "end": 1800
      },
      "initial_state": {
        "NO": 10,
        "NO2": 20,
        "O3": 70,
        "ISOP": 2,
        "OH": 4e-06,
        "HO2": 4e-06
      },
      "parameters": {
        "T": 298.0,
        "num_density": 40.896894217403165
      },
      "parameter_sweep": {
        "type": "cartesian",
        "dimensions": [
          {
            "parameter": "j_11",
            "values": [
              0.0,
              0.001,
              0.0025,
              0.005,
              0.0075,
              0.01,
              0.0149,
              0.02
            ]
          }
        ]
      },
      "plots": [
        {
          "id": "OH_vs_jNO2",
          "type": "line",
          "description": "Quasi-steady-state OH at t=1800 s vs NO2 photolysis rate j_11.",
          "x": {
            "variable": "j_11",
            "label": "j_11 (1/s)"
          },
          "y": {
            "variable": "OH",
            "label": "OH (ppb)"
          }
        },
        {
          "id": "O3_vs_jNO2",
          "type": "line",
          "description": "O3 at t=1800 s vs NO2 photolysis rate j_11 — quasi-steady-state ozone response across the dark-to-noon photolysis range.",
          "x": {
            "variable": "j_11",
            "label": "j_11 (1/s)"
          },
          "y": {
            "variable": "O3",
            "label": "O3 (ppb)"
          }
        }
      ]
    },
    {
      "id": "temperature_sweep",
      "description": "Tropospheric-temperature sensitivity at fixed polluted-urban composition and noon photolysis (j_11=0.0149 1/s). Sweeps T across the same 9-grid superfast uses (240 K cold upper-troposphere → 320 K warm boundary layer) and integrates each grid point for 1800 s (30 min — long enough for the slow O3 budget to respond), then plots the t=1800 s OH and O3 against T. The bimolecular Arrhenius rates and termolecular falloff rates that dominate the HOx, NOx and O3 budgets all carry strong T dependence; the 30-min window lets the net effect on tropospheric O3 emerge in a single curve. Note: num_density is held at 40.9 mol/m³ (the polluted_urban value) rather than scaling with T at fixed P, so the sweep isolates the rate-coefficient T dependence from the P/T density dependence.",
      "time_span": {
        "start": 0,
        "end": 1800
      },
      "initial_state": {
        "NO": 10,
        "NO2": 20,
        "O3": 70,
        "ISOP": 2,
        "OH": 4e-06,
        "HO2": 4e-06
      },
      "parameters": {
        "j_11": 0.0149,
        "num_density": 40.896894217403165
      },
      "parameter_sweep": {
        "type": "cartesian",
        "dimensions": [
          {
            "parameter": "T",
            "values": [
              240,
              250,
              260,
              270,
              280,
              290,
              300,
              310,
              320
            ]
          }
        ]
      },
      "plots": [
        {
          "id": "OH_vs_T",
          "type": "line",
          "description": "Quasi-steady-state OH at t=1800 s vs temperature T.",
          "x": {
            "variable": "T",
            "label": "Temperature (K)"
          },
          "y": {
            "variable": "OH",
            "label": "OH (ppb)"
          }
        },
        {
          "id": "O3_vs_T",
          "type": "line",
          "description": "O3 at t=1800 s vs temperature T — quasi-steady-state ozone response across the cold-troposphere-to-warm-boundary-layer range.",
          "x": {
            "variable": "T",
            "label": "Temperature (K)"
          },
          "y": {
            "variable": "O3",
            "label": "O3 (ppb)"
          }
        }
      ]
    }
  ]
}